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35
-
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13844252617
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note
-
a values for the protonated 3,5,7-trimethyl-1-aza- adamantanetrione, -dione, and -one are 0.3 (3:1 water/dioxane), 3.5, and 7.14, respectively (ref 14f).
-
-
-
-
36
-
-
13844291782
-
-
note
-
For example, treatment of 3,5,7-tripropyl-1-aza-adamantanetrione 11 (vide infra) with methyl iodide, hydrogen peroxide, or m-CPBA gives no reaction at the bridgehead nitrogen.
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37
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0242416948
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Simaan, S.; Siegel, J. S.; Biali, S. E. J. Org. Chem. 2003, 68, 3699-3701.
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0013370309
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Jeon, S.J.5
-
39
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0942299119
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Tamm, T.5
Karelson, M.6
-
40
-
-
13844293344
-
-
note
-
2 = 2.60 ppm; this value increases through the monoketone (2.88-3.03), diketone (2.75-3.45), and triketone (3.41) indicative of enhanced through-bond effects (data taken from ref 14).
-
-
-
-
42
-
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0036274287
-
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(b) Gronwald, O.; Snip, E.; Shinkai, S. Curr. Opin. Colloid Interface Sci. 2002, 7, 148-156.
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-
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Gronwald, O.1
Snip, E.2
Shinkai, S.3
-
44
-
-
13844251184
-
-
note
-
2 bond angle of 120°.
-
-
-
-
45
-
-
0030242269
-
-
For a discussion of gel morphology dependence on drying technique see: Frey, M. W.; Cuculo, J. A.; Spontak, R. J. J. Polym. Sci., Part B: Polym. Phys. 1996, 34, 2049-2058.
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-
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Frey, M.W.1
Cuculo, J.A.2
Spontak, R.J.3
-
47
-
-
13844288495
-
-
note
-
DSC analysis of the monomer reveals a sharp endothermic transition upon first heating (297.1°C) and sharp exotherm upon cooling (222.5°C). Likewise, preliminary powder X-ray diffraction studies show a series of low angle diffraction peaks that are not readily indexed.
-
-
-
-
48
-
-
13844293345
-
-
note
-
3 GB/SA solvation model. The structures were further minimized at the ab initio (HF/3-21G*) level using Gaussian 98 (Revision A.7, Gaussian, Inc.: Wallingford, CT, 2004). Details and references are provided in the Supporting Information.
-
-
-
-
49
-
-
13844265063
-
-
note
-
s-symmetric "all-arms-up" conformers bearing one disparate arm with φ ∼ -45° and ψ ∼ -90°.
-
-
-
-
51
-
-
13844268396
-
-
note
-
2Ar regions.
-
-
-
-
52
-
-
3042817445
-
-
and references therein
-
For comprehensive studies of dipolar aggregation phenomena in solution see: Yao, S.; Beginn, U.; Gress, T.; Lysetska, M.; Würthner, F. J. Am. Chem. Soc. 2004, 126, 8336-8348 and references therein.
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J. Am. Chem. Soc.
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Yao, S.1
Beginn, U.2
Gress, T.3
Lysetska, M.4
Würthner, F.5
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