Identification of the 1,2-propanediol-1-yl radical as an intermediate in adenosylcobalamin-dependent diol dehydratase reaction

Biochemistry

Volumn 44, Issue 6, 2005, Pages 2113-2118

  Yamanishi, Mamoru ^a   Ide, Hirofumi ^a   Murakami, Yoshitake ^a   Toraya, Tetsuo ^a  

^a OKAYAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMICAL REACTIONS; COUPLINGS; MECHANISMS; SPECTROSCOPIC ANALYSIS; SUBSTRATES; SYNTHESIS (CHEMICAL);

DEHYDRATASE PROCEEDS; HIGH-FIELD DOUBLET; RADICAL MECHANISM; SUBSTRATE-DERIVED RADICALS;

ORGANIC COMPOUNDS;

1,2 PROPANEDIOL 1 YL; COBALAMIN; COBALT; COBAMAMIDE; DIOL DEHYDRATASE; HYDROLYASE; ORGANIC COMPOUND; PROPANEDIOL DERIVATIVE; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON SPIN RESONANCE; ENZYME MECHANISM; ENZYME SUBSTRATE; ISOTOPE LABELING; NONHUMAN; PARAMETER; PRIORITY JOURNAL; REACTION ANALYSIS; SIGNAL DETECTION; SYNTHESIS;

BINDING SITES; CARBON ISOTOPES; COBAMIDES; DEUTERIUM EXCHANGE MEASUREMENT; ELECTRON SPIN RESONANCE SPECTROSCOPY; ENERGY METABOLISM; FREE RADICALS; HYDROGEN BONDING; KLEBSIELLA OXYTOCA; MODELS, MOLECULAR; PROPANEDIOL DEHYDRATASE; PROPYLENE GLYCOLS; SUBSTRATE SPECIFICITY;

EID: 13544256281     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi0481850     Document Type: Article

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