Suicide Inactivation of Dioldehydrase by 2-Chloroacetaldehyde: Formation of the 'cis-Ethanesemidione' Radical, and the Role of a Monovalent Cation

Helvetica Chimica Acta

Volumn 86, Issue 11, 2003, Pages 3764-3775

  Schwart, Phillip ^a   LoBrutto, Russell ^b   Reed, George H ^a   Frey, Perry A ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; CATALYSIS; DEHYDRATION; ELECTRONS; PROPANE;

INTERMEDIATES;

BIOCHEMISTRY;

5 DEOXYADENOSYL RADICAL; ALDEHYDE DERIVATIVE; CARBON; CHLOROACETALDEHYDE; COBALAMIN; COBALT; COBAMAMIDE; DIOL DEHYDRATASE; ENZYME; ETHANE; ETHANESEMIDIONE; GLYCOLALDEHYDE; HISTIDINE; HYDROCHLORIC ACID; MONOVALENT CATION; POTASSIUM; PROPIONALDEHYDE; PROPYLENE GLYCOL; RADICAL; SUICIDE SUBSTRATE; THALLIUM; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; ELECTRON; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYME ACTIVITY; ENZYME INACTIVATION; MAGNETIC FIELD; MOLECULAR INTERACTION; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0346121375     PISSN: 0018019X     EISSN: None     Source Type: Journal    
DOI: 10.1002/hlca.200390318     Document Type: Article

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