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In addition to the arenediazonium salts and aryltriazenes as the main subject of this paper, arylammonium salts have been recently used for the Suzuki - Miyaura-type coupling reaction: Blakey, S. B.; MacMillan, D. W. C. J. Am. Chem. Soc. 2003, 125, 6046.
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1342305875
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note
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Triazenes having a diethylamino or morpholino moiety at the 3-position were less effective under the reaction conditions, and areneboronic esters were completely inert.
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23
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1342284684
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note
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The competitive reaction of aryltriazene 1 with p-bromotoluene in the reaction with areneboronic acid 2 afforded biphenyl product 3 in 90% yield, together with the aryl bromide being recovered unchanged.
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24
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1342284685
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note
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Chemoselective differential reactions of 4-bromobenzene diazonium salt and 4-bromophenyltriazene have been already reported; see refs 4a,d and 6c.
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25
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1342327205
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note
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An increased amount of catalyst (5 mol %) without phosphine ligand was necessary: only a trace amount of product was obtained in the presence of phosphine ligand. The reason is not clear.
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26
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34249066760
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