An N-heterocyclic carbene/iridium hydride complex from the oxidative addition of a ferrocenyl-bisimidazolium salt: Implications for synthesis

Angewandte Chemie - International Edition

Volumn 44, Issue 3, 2005, Pages 444-447

  Viciano, Mónica ^a   Mas Marzá, Elena ^a   Poyatos, Macarena ^a   Sanaú, Mercedes ^b   Crabtree, Robert H ^c   Peris, Eduardo ^a  

^a UNIVERSITAT JAUME I   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

^c YALE UNIVERSITY   (United States)

Author keywords

C H activation; Carbene ligands; Hydrides; Iridium; Rhodium

Indexed keywords

ADDITION REACTIONS; COMPLEXATION; CRYSTAL STRUCTURE; NITROGEN COMPOUNDS; OXIDATION; SODIUM CHLORIDE; X RAY CRYSTALLOGRAPHY;

DEPROTONATION; IMIDAZOLIUM SALT; OXIDATIVE ADDITION; X-RAY CRYSTAL STRUCTURES;

IRIDIUM COMPOUNDS;

CARBENOID; FERROCENE DERIVATIVE; HYDROGEN; IMIDAZOLE DERIVATIVE; IRIDIUM COMPLEX; LIGAND; PHOSPHINE DERIVATIVE; SODIUM CHLORIDE;

ADDITION REACTION; ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CONFORMATIONAL TRANSITION; CORRELATION ANALYSIS; CYCLIZATION; DEPROTECTION REACTION; MOLECULAR DYNAMICS; OXIDATION KINETICS; PHASE SEPARATION; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; SIGNAL TRANSDUCTION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 12344320589     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461918     Document Type: Article

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