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For some selected recent work see: R. Jackstell, S. Harkal, H. Jiao, A. Spannenberg, C. Borgmann, D. Röttger, F. Nierlich, M. Elliot, S. Niven, K. Cavell, O. Navarro, M.S. Viciu, S.P. Nolan, and M. Beller Chem. Eur. J. 10 2004 3891 3900
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32
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12344284190
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note
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All experiments were carried out under an inert gas atmosphere (argon) with exclusion of air. For the standard reaction procedure NaOH or sodium is dissolved in 4 mL of iso-propanol at 90°C in a double walled thermostated reaction vessel. The solution containing the catalyst and the ligand in 1 mL iso-propanol is prepared in a Schlenk tube and added to the reaction vessel at 90°C via septa and a small teflon tube after refluxing became stationary. Starting with addition of the catalyst the progress of the reaction is followed by several analytical methods. The amount of generated hydrogen is measured by gas burette. In addition a hydrogen sensor of the Fa. Hach Ultra Analytics GmbH is used for analysis of hydrogen and a GC for analyzing gases is applied (gas chromatograph HP 5890, permanent gases: Carboxen 1000, TCD, external calibration; alkanols, aldehydes/ketones: HP Plot Q, 30 m, FID). Aldol condensation products and hydrogenation of the aldol condensation products are analyzed by gas chromatography (HP 1, 50 m, FID, internal standard). The reproducibility of the results is between 12% and 15%
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33
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0041335604
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C. Carlini, M.D. Girolamo, A. Macinai, M. Marchionna, M. Noviello, A.M. Raspolli Galletti, and G. Sbrana J. Mol. Catal. 204 2003 721 728
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Carlini, C.1
Girolamo, M.D.2
MacInai, A.3
Marchionna, M.4
Noviello, M.5
Raspolli Galletti, A.M.6
Sbrana, G.7
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34
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0141451741
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C. Carlini, A. Macinai, M. Marchionna, M. Noviello, A.M. Raspolli Galletti, and G. Sbrana J. Mol. Catal. 206 2003 409 418
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MacInai, A.2
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Noviello, M.4
Raspolli Galletti, A.M.5
Sbrana, G.6
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35
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0001211425
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This ligand is commercially available from Degussa and Strem under the name CataCXium A. For some catalytic application see: A. Zapf, A. Ehrentraut, and M. Beller Angew. Chem. 112 2000 4315 4317
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Beller, M.3
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J.P. Wolfe, R.A. Singer, B.H. Yang, and St. L. Buchwald J. Am. Chem. Soc. 121 41 1999 9550 9561
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Yang, B.H.3
Buchwald St., L.4
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43
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1642580702
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This and similar ligands are commercially available from Degussa and Strem under the name CataCXium P. For some catalytic application see: A. Zapf, R. Jackstell, F. Rataboul, T. Riermeier, A. Monsees, C. Fuhrmann, N. Shaikh, U. Dingerdissen, and M. Beller Chem. Commun. 2004 38 39
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Chem. Commun.
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Zapf, A.1
Jackstell, R.2
Rataboul, F.3
Riermeier, T.4
Monsees, A.5
Fuhrmann, C.6
Shaikh, N.7
Dingerdissen, U.8
Beller, M.9
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44
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3042819291
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F. Rataboul, A. Zapf, R. Jackstell, T. Riermeier, A. Monsees, U. Dingerdissen, and M. Beller Chem. Eur. J. 10 2004 2983 2990
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Zapf, A.2
Jackstell, R.3
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Dingerdissen, U.6
Beller, M.7
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B.A. Persson, A.L.E. Larsson, M. Le Ray, and J.-E. Bäckvall J. Am. Chem. Soc. 121 8 1999 1645 1650
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