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Volumn 43, Issue 26, 2004, Pages 8394-8403

Chiral organometallic triangles with Rh-Rh bonds. 1. Compounds prepared from racemic cis-Rh2(C6H4PPh2) 2(OAc)2

Author keywords

[No Author keywords available]

Indexed keywords

4,4' BIPHENYL DICARBOXYLATE; ANION; DICARBOXYLIC ACID DERIVATIVE; LIGAND; ORGANIC SOLVENT; ORGANOMETALLIC COMPOUND; OXALIC ACID; PHOSPHINE; RHODIUM DERIVATIVE; TEREPHTHALIC ACID; TETRYLAMMONIUM; UNCLASSIFIED DRUG;

EID: 11144338877     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0492183     Document Type: Article
Times cited : (59)

References (84)
  • 46
    • 0003548528 scopus 로고    scopus 로고
    • For reviews of chirality at metal centers, see for example: (a) Keene, F. R. Coord. Chem. Rev. 1997, 166, 121.
    • (1997) Coord. Chem. Rev. , vol.166 , pp. 121
    • Keene, F.R.1
  • 53
    • 11144318975 scopus 로고    scopus 로고
    • Bruker Advanced X-ray Solutions, Inc.: Madison, WI
    • SMART for Windows NT, Version 5.618; Bruker Advanced X-ray Solutions, Inc.: Madison, WI, 2001.
    • (2001) SMART for Windows NT, Version 5.618
  • 56
    • 0004150157 scopus 로고    scopus 로고
    • Advanced X-ray Solutions, Inc.: Madison, WI
    • Sheldrick, G. M. SHELXTL, Version 6.12; Advanced X-ray Solutions, Inc.: Madison, WI, 2002.
    • (2002) SHELXTL, Version 6.1
    • Sheldrick, G.M.1
  • 64
    • 84981828672 scopus 로고
    • In a helical system, P stands for plus and M for minus as they relate to the torsion angles along the axis of the helix. For the conformers in 1, this axis coincides with the Rh-Rh bond. See for example: (a) Cahn, R. S.; Ingold, C.; Prelog, V. Angew. Chem., Int. Ed. Engl. 1966, 5, 385.
    • (1966) Angew. Chem., Int. Ed. Engl. , vol.5 , pp. 385
    • Cahn, R.S.1    Ingold, C.2    Prelog, V.3
  • 68
    • 11144303808 scopus 로고    scopus 로고
    • note
    • 2 and its analogues in ref 18. We believe that our labeling system is more descriptive because it considers the two sources of chirality found in this type of molecule.
  • 72
    • 11144339728 scopus 로고    scopus 로고
    • See also ref 29c
    • (d) See also ref 29c).
  • 83
    • 11144325974 scopus 로고    scopus 로고
    • note
    • 2 units in 4 appear closer to having an eclipsed structure. The average of C-Rh-Rh-P is 9.0°. The value of 0.6° for the O-Rh-Rh-O angle is very close to that in an eclipsed species.
  • 84
    • 11144293033 scopus 로고    scopus 로고
    • note
    • 2O, were present in the NMR solvent.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.