A novel organometallic macrocycle composed of a tetranuclear palladium acetylide

Angewandte Chemie - International Edition

Volumn 38, Issue 1-2, 1999, Pages 174-176

  Onitsuka, Kiyotaka ^a   Yamamoto, Shin ^a   Takahashi, Shigetoshi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Alkyne complexes; Macrocycles; Metallacycles; Palladium

Indexed keywords

MACROCYCLIC COMPOUND; ORGANOMETALLIC COMPOUND; PALLADIUM COMPLEX;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; COMPLEX FORMATION; CRYSTAL STRUCTURE; MOLECULAR DYNAMICS; X RAY CRYSTALLOGRAPHY;

EID: 0033555218     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990115)38:1/2<174::AID-ANIE174>3.0.CO;2-I     Document Type: Article

References (24)

1. Recent reviews: a) Comprehensive Supramolecular Chemistry (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol, F. Vögtle, K. S. Suslick), Pergamon, Oxford, 1996;
2. b) J.-M. Lehn, Supramolecular Chemistry, Concepts and Perspectives, VCH, Weinheim, 1995.
3. Recent reviews: a) M. Fujita, K. Ogura, Bull. Chem. Soc. Jpn. 1996, 69, 1471;
4. b) P. J. Stang, B. Olenyuk, Acc. Chem. Res. 1997, 30, 502.
5. a) N. Hagihara, K. Sonogashira, S. Takahashi, Adv. Polym. Sci. 1981, 41, 149;
6. b) N. Ohshiro, F. Takei, K. Onitsuka, S. Takahashi, Chem. Leu. 1996, 871;
7. c) K. Onitsuka, Y. Harada, F. Takei, S. Takahashi, Chem. Commun. 1998, 643.
8. H. Lang, Angew. Chem. 1994, 106, 569: Angew. Chem. Int. Ed. Engl. 1994, 33, 547, and references therein.
9. H. Lang, Angew. Chem. 1994, 106, 569: Angew. Chem. Int. Ed. Engl. 1994, 33, 547, and references therein.
10. a) R. Faust, F. Diederich, V. Gramlich, P. Seiler, Chem. Eur. J. 1995, 1, 111;
11. b) D. Zhang, D. B. McConville, C.A. Tessier, Y. J. Youngs, Organometallics 1997, 16, 824;
12. c) J. J. Pak, T. J. R. Weakley, M. M. Haley, Organometallics 1997, 16, 4505.
13. L. G. Mackay, H. L. Anderson, J. K. M. Sanders, J. Chem. Soc. Perkin Trans, 1 1995, 2269.
14. S. Takahashi, Y. Kuroyama, K. Sonogashira, N. Hagihara, Synthesis 1980, 627.
15. [13b]
16. a) U. Behrens, K. Hoffmann, J. Organomet. Chem. 1977, 129, 273;
17. b) K. Onitsuka, H. Ogawa, T. Joh, S. Takahashi, Y. Yamamoto, H. Yamazaki, J. Chem. Soc. Dalton Trans. 1991, 1531.
18. U. Behrens, K. Hoffmann, J. Kopf, J. Morits, J. Organomet. Chem. 1976, 117, 91.
19. R. Nast, V. Pank, J. Organomet. Chem. 1977, 129, 265.
20. a) F. Diederich, Y. Rubin, Angew. Chem. 1992, 104, 1123; Angew. Chem. Int. Ed. Engl. 1992, 31, 1101;
21. a) F. Diederich, Y. Rubin, Angew. Chem. 1992, 104, 1123; Angew. Chem. Int. Ed. Engl. 1992, 31, 1101;
22. b) M. M. Haley, Synlett 1998, 557.
23. w = 0.110 for 244 parameters against 2711 reflections with 1 > 3.0σ(1) out of 4573 unique reflections by full-matrix least-squares method, GOF 1.24.
24. b) Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-101 904 (1a) and CCDC-101 905 (2). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+ 44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).