Synthesis and X-ray structure of metalated Rhodium(II) catalysts with a chiral phospholane

European Journal of Inorganic Chemistry

Volumn , Issue 1, 2001, Pages 105-109

  Estevan, Francisco ^a   Krueger, Peter ^b   Lahuerta, Pascual ^a   Moreno, Eduardo ^a   Pérez Prieto, Julia ^a   Sanaú, Mercedes ^a   Werner, Helmut ^b  

^a UNIVERSITY OF VALENCIA   (Spain)

^b UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Carbocycles; Chirality; Diazo compounds; P ligands; Rhodium

Indexed keywords

CHELATION; CHROMATOGRAPHIC ANALYSIS; X RAY ANALYSIS;

CARBOCYCLES; CHROMATOGRAPHIC METHODS; CRYSTALLOGRAPHIC PARAMETERS; CYCLIZATIONS; DIASTEREOISOMERS; DIAZO COMPOUNDS; P LIGANDS; PHOSPHANES; X-RAY STRUCTURE; ]+ CATALYST;

RHODIUM COMPOUNDS;

RHODIUM DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHIRALITY; CRYSTAL STRUCTURE; CYCLIZATION; DIASTEREOISOMER; SYNTHESIS;

EID: 0035188393     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(20011)2001:1<105::aid-ejic105>3.0.co;2-y     Document Type: Article

References (33)

1. A. R. Chakravarty, F. A. Cotton, D. A. Tocher, J. H. Tocher, Organometallics 1985, 4, 8.
2. [2a] F. Barceló, F. A. Cotton, P. Lahuerta, R. Llusar, M. Sanaú, W. Schwotzer, M. A. Ubeda, Organometallics 1986, 5, 808.
3. [2b] F. Barceló, F. A. Cotton, P. Lahuerta, M. Sanaú, W. Schwotzer, M. A. Ubeda, Organometallics 1987, 6, 1105.
4. [2c] F. A. Cotton, P. Lahuerta, J. Payá, F. Barceló, M. A. Ubeda, Inorg. Chem. 1988, 27, 1010.
5. [2d] P. Lahuerta, J. Payá, X. Solans, M. A. Ubeda, Inorg. Chem. 1992, 31, 385.
6. [2e] P. Lahuerta, E. Peris, M. A. Ubeda, S. García-Granda, M. R. Díaz, J. Organomet. Chem. 1993, 455, C10.
7. [2f] F. Estevan, G. Gonzalez, P. Lahuerta, M. Martinez, E. Peris, R. van Eldik, J. Chem. Soc., Dalton Trans. 1996, 1045.
8. [3a] E. C. Morrison, D. A. Tocher, J. Organomet. Chem.1991, 408, 105.
9. [3b] E. C. Morrison, D. A. Tocher, Inorg. Chim. Acta 1989, 157, 139.
10. M. V. Borrachero, F. Estevan, S. García-Granda, P. Lahuerta, J. Latorre, E. Peris, M. Sanaú, J. Chem. Soc., Chem. Commun. 1993, 24, 1864.
11. [5a] G. González, P. Lahuerta, M. Martinez, E. Peris, M. Sanaú, J. Chem. Soc., Dalton Trans 1994, 545.
12. [5b] G. González, M. Martinez, F. Estevan, A. García-Bernabé, P. Lahuerta, E. Peris, M. A. Ubeda, R. Diaz, S. García-Granda, B. Tejerina, New J. Chem. 1996, 20, 83.
13. M. P. Doyle, M. A. McKervey, Chem. Commun. 1997, 983.
14. [7a] F. Estevan, P. Lahuerta, J. Pérez-Prieto, S. E. Stiriba, M. A. Ubeda, Synlett 1995, 11, 1121.
15. [7b] F. Estevan, P. Lahuerta, J. Pérez-Prieto, M. Sanaú, S. E. Stiriba, M. A. Ubeda, Organometallics 1997, 16, 880.
16. [8a] S. Hashimoto, N. Watanabe, S. Ikegami, Tetrahedron Lett. 1990, 31, 5173.
17. [8b] M. Anada, S. Hashimoto, Tetrahedron Lett. 1998, 39, 79.
18. [9a] M. P. Doyle, W. R. Winchester, J. A. A. Hoorn, V. Lynch, S. H. Simonsen, R. Ghosh, J. Am. Chem. Soc. 1993, 115, 9968.
19. [9b] M. P. Doyle, Q-L. Zhov, A. B. Dyatkin, D. A. Ruppar, Tetrahedron Lett. 1995, 36, 7579.
20. D. F. Taber, S. C. Malcolm, K. Bieger, P. Lahuerta, M. Sanaú, S. E. Stiriba, J. Pérez-Prieto, M. A. Monge, J. Am. Chem. Soc. 1999, 121, 860.
21. P. Müller, P. Polleaux, Helv. Chim. Acta 1994, 77, 645.
22. M. P. Doyle, M. Y. Eismont, Q. L. Zhou, Russ. Chem. Bull. 1997, 46, 955.
23. F. A. Cotton, R. A. Walton, Multiple Bonds Between Metal Atoms; Clarendon Press, Oxford, 1993.
24. M. P. Doyle, D. C. Forbes, Chem. Rev. 1998, 95, 911.
25. The ee values were based on GC analysis with a 2,3-di-O-acetyl 6-O-tert-butyldimethylsilyl beta CDX column.
26. The absolute configuration of 8 was determined by correlation of the sign of the rotation of polarized light with that of the known enantiomer: L. A. Paquette, J. P. Gilday, C. S. Ra, J. Am. Chem. Soc. 1987, 109, 6858.
27. The absolute configuration of 10 was determined by correlation of the sign of the rotation of polarized light with that of the known enantiomer: [17a] D. A. Lighter, D. E. Jackman, Tetrahedron Lett. 1975, 3051.
28. [17b] E. A. March, K. A. Nelson, Tetrahedron 1987, 43, 679.
29. [18a] M. J. Burk, J. E. Feaster, R. L. Harlow, Tetrahedron: Asymmetry 1991, 2, 569.
30. [18b] M. J. Burk, J. E. Feaster, R. L. Harlow, J. Am. Chem. Soc. 1990, 115, 10125-10138.
31. [18c] M. J. Burk, J. E. Feaster, R. L. Harlow, Organometallics 1990, 9, 2653.
32. S. A. Johnson, H. R. Hunt, H. M. Neumann, Inorg. Chem. 1963, 2, 960.
33. SHELXTL V 5.05, AXS Siemens, 1996.