Direct catalytic enantioselective α-aminomethylation of ketones

Angewandte Chemie - International Edition

Volumn 43, Issue 47, 2004, Pages 6528-6531

  Ibrahem, Ismail ^a   Casas, Jesús ^a   Córdova, Armando ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

Amino alcohols; Asymmetric catalysis; Ketones; Mannich reaction

Indexed keywords

ALCOHOLS; AMINO ACIDS; CHEMICAL REACTIONS; KETONES; SYNTHESIS (CHEMICAL);

1,3-AMINO ALCOHOLS; PROLINE-CATALYZED MANNICH REACTION; SYNTHETIC BUILDING BLOCKS;

CATALYSIS;

AMINE; KETONE;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; ECONOMIC ASPECT; ENANTIOSELECTIVITY; MANNICH REACTION; METHYLATION; ROOM TEMPERATURE; STOICHIOMETRY;

EID: 11144333506     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460678     Document Type: Article

References (124)

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48. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
49. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
50. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
51. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
52. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
53. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
54. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
55. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
56. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
57. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
58. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
59. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
60. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
61. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F.
62. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
63. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
64. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
65. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
66. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
67. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
68. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
69. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
70. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
71. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
72. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
73. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
74. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
75. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
76. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
77. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu,
78. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
79. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
80. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
81. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
82. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
83. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
84. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
85. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
86. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
87. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
88. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
89. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
90. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
91. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
92. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
93. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003,
94. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
95. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
96. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
97. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
98. Aldol reactions see: a) B. List, R. A. Lerner, C. F. Barbas III, J. Am. Chem. Soc. 2000, 122, 2395; b) W. Notz, B. List, J. Am. Chem. Soc. 2000, 122, 7386; c) K. Saktihvel, W. Notz, T. Bui, C. F. Barbas III, J. Am. Chem. Soc. 2001, 123, 5260; d) A. Córdova, W. Notz, C. F. Barbas III, J. Org. Chem. 2002, 67, 301; e) B. List, P. Pojarliev, C. Castello, Org. Lett. 2001, 3, 573; f) A. Córdova, W. Notz, C. F. Barbas III, Chem. Commun. 2002, 67, 3034; g) A. Bøgevig, K. Juhl, N. Kumaragurubaran, K. A. Jørgensen, Chem. Commun. 2002, 620; h) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 6798; i) N. S. Chowdari, D. B. Ramachary, A. Córdova, C. F. Barbas III, Tetrahedron Lett. 2002, 43, 9591; j) C. Pidathala, L. Hoang, N. Vignola, B. List, Angew. Chem. 2003, 115, 2797; Angew. Chem. Int. Ed. 2003, 42, 2785; k) Z. Tang, F. Jiang, L.-T. Yu, X. Cui, L.-Z. Gong, A.-Q. Mi, Y.-Z. Jiang, Y.-D. Wu, J. Am. Chem. Soc. 2003, 125, 5262; α-Aminations see: a) A. Bøgevig, K. Juhl, N. Kumaragurubaran, W. Zhuang, K. A. Jørgensen, Angew. Chem. 2002, 114, 1868; Angew. Chem. Int. Ed. 2002, 41, 1790; b) B. List, J. Am. Chem. Soc. 2002, 124, 5656; c) N. Kumaragurubaran, K. Juhl, W. Zhuang, A. Bøgevig, K. A. Jørgensen, J. Am. Chem. Soc. 2002, 124, 6254; α-Oxidations see: a) A. Bøgevig, H. Sundén, A. Córdova, Angew. Chem. 2004, 116, 1129; Angew. Chem. Int. Ed. 2004, 43, 1109; b) M. Hayashi, J. Yamaguchi, T. Sumaiya, M. Shoji, Angew. Chem. 2004, 116, 1132; Angew. Chem. Int. Ed. 2004, 43, 1112; c) G. Zhong, Angew. Chem. 2003, 115, 4379; Angew. Chem. Int. Ed. 2003, 42, 4247; d) S. P. Brown, M. P. Brochu, C. J. Sinz, D. W. C. MacMillan, J. Am. Chem. Soc. 2003, 125, 10808; Michael reactions see: a) B. List, P. Pojarliev, H. J. Martin, Org. Lett. 2001, 3, 2423; b) S. Hanessian, V. Pham, Org. Lett. 2000, 2, 2975; c) J. M. Betancort, K. Sakthivel, R. Thayumanavan, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 4441; d) J. M. Betancort, C. F. Barbas III, Org. Lett. 2001, 3, 3737; e) D. J. Hortsmann, D. J. Guerin, S. J. Miller, Angew. Chem. 2000, 112, 3781; Angew. Chem. Int. Ed. 2000, 39, 3635; f) A. Alexakis, O. Andrey, Org. Lett. 2002, 4, 3611; g) D. J. Guerin, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 2134; h) N. Halland, P. S. Aburel, K. A. Jørgensen, Angew. Chem. 2003, 115, 685, Angew. Chem. Int. Ed. 2003, 42, 661; i) N. Halland, R. G. Hazell, K. A. Jørgensen, J. Org. Chem. 2002, 67, 8331; j) O. Andrey, A. Alexakis, G. Bernardinelli, Org. Lett. 2003, 5, 2559; k) D. Enders, A. Seki, Synlett 2002, 26; Diels-Alder reactions see: a) A. B. Northrup, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 2458; b) K. A. Ahrendt, C. J. Borths, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 4243; hetero-Diels-Alder reactions see: a) K. Juhl, K. A. Jørgensen, Angew. Chem. 2003, 115, 1536; Angew. Chem. Int. Ed. 2003, 42, 1498; b) Y. Huang, K. Unni, A. N. Thadani, V. H. Rawal, Nature 2003, 424, 146; alkylation of electron-rich benzene systems see: a) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2001, 123, 4370; b) J. F. Austin, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 1172; c) N. A. Paras, D. W. C. MacMillan, J. Am. Chem. Soc. 2002, 124, 7894; 1,3-dipolar cycloadditions see: a) W. S. Jen, J. J. M. Wiener, D. W. C. MacMillan, J. Am. Chem. Soc. 2000, 122, 9874; b) S. Karlsson, H. Högberg, Tetrahedron: Asymmetry 2002, 13, 923; other reactions see: a) A. E. Taggi, A. M. Hafez, H. Wack, B. Young, W. J. Drury III, T. Lectka, J. Am. Chem. Soc. 2000, 121, 7831; b) B. R. Sculimbrene, A. J. Morgan, S. J. Miller, J. Am. Chem. Soc. 2002, 124, 11653; c) M. Harmata, S. K. Ghosh, X. Hong, S. Wacharasindhu, P. Kirchhoefer, J. Am. Chem. Soc. 2003, 125, 2058; d) N. Bremeyer, S. C. Smith, S. V, Ley, M. J. Gaunt, Angew. Chem. 2004, 116, 2735; Angew. Chem. Int. Ed. 2004, 43, 2681.
99. a) B. List, J. Am. Chem. Soc. 2000, 122, 9336;
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101. W. Notz, K. Sakthivel, T. Bui, G. Zhong, C. F. Barbas III, Tetrahedron Lett. 2001, 42, 199.
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103. a) A. Córdova, S. Watanabe, F. Tanaka, W. Notz, C. F. Barbas III, J. Am. Chem. Soc. 2002, 124, 1866;
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121. The compounds are sensitive and racemize upon column chromatography with silica gel as the stationary phase. The Mannich base products should be stored at -35°C.
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