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Volumn 121, Issue 23, 2004, Pages 11965-11979

Inelastic electron tunneling spectroscopy in molecular junctions: Peaks and dips

Author keywords

[No Author keywords available]

Indexed keywords

INELASTIC ELECTRON TUNNELING SPECTROSCOPY; MOLECULAR WIRE JUNCTIONS; WIRE LENGTH;

EID: 11044221428     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1814076     Document Type: Article
Times cited : (330)

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    • M. Galperin, M. A. Ratner, and A. Nitzan (unpublished)
    • M. Galperin, M. A. Ratner, and A. Nitzan (unpublished).
  • 79
    • 36749120888 scopus 로고
    • In reality our primary phonons are molecular vibrational modes whose frequencies are larger than the environmental (secondary phonon) Debye frequency and their thermal relaxation is caused by nonlinear coupling to this environment. Still, Eq. (19) may be assumed to hold, with the parameter gij calculated from the appropriate nonlinear theory; see e.g., A. Nitzan, S. Mukamel, and J. Jortner, J. Chem. Phys. 63, 200 (1975).
    • (1975) J. Chem. Phys. , vol.63 , pp. 200
    • Nitzan, A.1    Mukamel, S.2    Jortner, J.3
  • 83
    • 11044228264 scopus 로고    scopus 로고
    • note
    • The failure of the SCBA procedure, which is based on the Migdal theorem, is to be expected when the electron-phonon coupling is large compared to the coupling to the contacts (see, e.g., Ref. 49). Such cases can in principle be treated by linked-cluster (Ref. 50) or Pade-approximants (Ref. 49) expansions.
  • 87
    • 11044233097 scopus 로고    scopus 로고
    • note
    • Lifetimes of high frequency molecular vibrational modes in low temperature environments are usually considerably longer than a picosecond.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.