Solvent-ligated manganese (II) complexes for the homopolymerization of isobutene and the copolymerization of isobutene and isoprene

Chemistry - A European Journal

Volumn 10, Issue 24, 2004, Pages 6323-6332

  Vierle, Mario ^a   Zhang, Yanmei ^a   Santos, Ana M ^a   Köhler, Klaus ^a   Haeßner, Carmen ^a   Herdtweck, Eberhardt ^a   Bohnenpoll, Martin ^b   Nuyken, Oskar ^a   Kühn, Fritz E ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b Formerly Baver Material Science AG   (Germany)

Author keywords

Copolymerization; Manganese; Polyisobutenes; Polymerization

Indexed keywords

BUTANE; CATALYST ACTIVITY; COORDINATION REACTIONS; COPOLYMERIZATION; HOMOPOLYMERIZATION; INITIATORS (CHEMICAL); MANGANESE; SUBSTRATES; THERMAL EFFECTS;

HOMOGENEOUS SOLUTIONS; ISOPRENES; LIGANDS; POLYISOBUTENES;

COMPLEXATION;

ISOBUTYLENE; ISOPRENE; MANGANESE DERIVATIVE; NITRILE; SOLVENT;

ARTICLE; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; OLEFINATION; POLYMERIZATION; TEMPERATURE DEPENDENCE;

EID: 10944237880     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400446     Document Type: Article

References (86)

1. a) W. Henke, Justus Liebigs Ann. Chem. 1858, 106, 280;
2. b) J. Hathaway, A. E. Underbill, J. Chem. Soc. 1960, 3705;
3. c) J. Hathaway, D. G. Holah, A. E. Underbill, J. Chem. Soc. 1962, 2444;
4. d) J. Hathaway, D. G. Holah, J. Chem. Soc. 1964, 2400;
5. e) J. P. Fackler, D. G. Holah, Inorg. Chem. 1965, 4, 945;
6. f) R. A. Walton, Q. Rev. Chem. Soc. 1965, 19, 126;
7. g) A. P. Zuur, W. L. Groeneveld, Recl Trav. Chim. Pays-Bas 1967, 86, 1103;
8. h) J. Reedijk, A. P. Zuur, W. L. Groeneveld, Recl. Trav. Chim. Pays-Bas 1967, 86, 1103;
9. J. Reedijk, W. L. Groenenveld, Recl. Trav. Chim. Pays-Bas 1968, 87, 513;
10. j) J. Reedijk, N. S. Angerman, R. B. Jordan, Inorg. Chem. 1969, 8, 65;
11. k) J. Reedjik, Recl Trav. Chim. Pays-Bas 1969, 88, 86;
12. l) A. de Renzi, A. Panunzi, A. Vitagliano, G. Paiaro, J. Chem. Soc. Chem. Commun. 1976, 47;
13. m) P. R. Johnson, J. M. Pratt, R. I. Tilley, J. Chem. Soc. Chem. Commun. 1978, 606;
14. n) A. Monnerat, P. Moore, K. Newman, A. E. Merbach, Inorg. Chim. Acta 1981, 47, 139;
15. o) J. A. Davies, F. R. Hartley, Chem. Rev. 1981, 81, 79;
16. p) M. J. Sisley, Y. Yano, T. W. Swaddle, Inorg. Chem. 1982, 21, 1141;
17. q) K. Nielsson, A. Oskarsson, Acta. Chem. Scand. A. 1984, 38, 79;
18. r) R. R. Thomas, V. Chebolu, A. Sen, J. Am. Chem. Soc. 1986, 108, 4096;
19. s) A. Bruckner, H. Vogt, L. Riesel, Z. Chem. 1987, 27, 415;
20. t) M. Bown, X. R. L. Fontaine, N. N. Greenwood, J. D. Kennedy, M. J. Thornton-Pett, J. Chem. Soc. Dalton Trans. 1987, 1169;
21. u) I. Rapaport, L. Helm, A. E. Merbach, P. Bernhard, A. Ludi, Inorg. Chem. 1988, 27, 873;
22. v) M. Ishii, S. Funahashi, K. Ishihara, M. Tanaka, Bull. Chem. Soc. Jpn. 1989, 62, 1852;
23. w) R. R. Thomas, A. Sen, Inorg. Synth. 1989, 26, 128;
24. x) R. T. Henriques, E. Herdtweck, F. E. Kühn, A. D. Lopes, J. Mink, C. C. Romão, J. Chem. Soc. Dalton Trans. 1998, 1293;
25. y) W. E. Buschmann, J. S. Miller, Chem. Eur. J. 1998, 4, 1731.
26. a) J. M. Mayer, E. H. Abbott, Inorg. Chem. 1983, 22, 2774;
27. b) K. R. Dunbar, J. Am. Chem. Soc. 1988, 110, 8247;
28. c) L. M. Dikareva, V. I. Andrianov, A. N. Zhilyaev, I. B. Baranovskii, Russ. J. Inorg. Chem. 1989, 34, 4096;
29. d) F. A. Cotton, K. J. Wiesinger, Inorg. Chem. 1991, 30, 871;
30. e) S. N. Bernstein, K. R. Dunbar, Angew. Chem. 1992, 104, 1412; Angew. Chem. Int. Ed. Engl. 1992, 31, 1360;
31. e) S. N. Bernstein, K. R. Dunbar, Angew. Chem. 1992, 104, 1412; Angew. Chem. Int. Ed. Engl. 1992, 31, 1360;
32. f) F. A. Cotton, S. C. Haefner, A. P. Sattelberger, J. Am. Chem. Soc. 1996, 118, 5486;
33. g) F. A. Cotton, F. E. Kühn, J. Am. Chem. Soc. 1996, 118, 5826.
34. a) M. McCann, P. Guinan, Polyhedron 1991, 10, 2283;
35. b) P. Guinan, M. McCann, H. Ryan, Polyhedron 1992, 11, 205;
36. c) M. McCann, E. M. G. Coda, K. Maddock, J. Chem. Soc. Dalton Trans. 1994, 1489;
37. d) M. McCann, E. M. G. Coda, J. Mol. Catal. 1996, 109, 99;
38. e) E. Whelan, M. Devereux, M. McCann, V. McKee, Chem. Commun. 1997, 427;
39. f) M. McCann, F. Humphreys, V. McKee, Polyhedron 1997, 16, 3655;
40. g) M. McCann in Catalysis by Di- and Polynuclear Metal Cluster Complexes (Eds.: R. D. Adams, F. A. Cotton), Wiley-VCH, New York, 1998, pp. 145-166.
41. h) F. E. Kühn, J. R. Ismeier, D. Schön, W. M. Xue, G. Zhang, O. Nuyken, Macromol. Rapid Commun. 1999, 20, 555;
42. i) F. E. Kühn, D. Schön, G. Zhang, O. Nuyken, J. Macromol. Sci. Pure Appl. Chem. 2000, 37, 971;
43. j) M. Pillinger, I. S. Gonçalves, A. A. Valente, P. Ferreira, D. Schön, O. Nuyken, F. E. Kühn, Des. Monomers Polym. 2001, 4, 269;
44. k) M. Pillinger, I. S. Gonçalves, P. Ferreira, J. Rocha, M. Schäfer, D. Schön, O. Nuyken, F. E. Kühn, Macromol. Rapid Commun. 2001, 22, 1306;
45. l) P. Ferreira, F. E. Kühn, Trends Inorg. Chem. 2001, 7, 89;
46. m) M. Pillinger, I. S. Gonçalves, A. D. Lopes, P. Ferreira, J. Rocha, G. Zhang, M. Schäfer, O. Nuyken, F. E. Kühn, Phys. Chem. Chem. Phys. 2002, 4, 696;
47. n) M. Pillinger, C. D. Nunes, P. D. Vaz, A. A. Valente, I. S. Gonçalves, P. J. A. Ribeiro-Claro, J. Rocha, L. D. Carlos, F. E. Kühn, Phys. Chem. Chem. Phys. 2002, 4, 3098;
48. o) D. Schön, PhD Thesis, TU München, 2001.
49. a) M. Vierle, Y. Zhang, E. Herdtweck, M. Bohnenpoll, O. Nuyken, F. E. Kühn, Angew. Chem. 2003, 115, 1345; Angew. Chem. Int. Ed. 2003, 42, 1307;
50. a) M. Vierle, Y. Zhang, E. Herdtweck, M. Bohnenpoll, O. Nuyken, F. E. Kühn, Angew. Chem. 2003, 115, 1345; Angew. Chem. Int. Ed. 2003, 42, 1307;
51. b) M. Bohnenpoll, J. Ismeier, O. Nuyken, M. Vierle, D. K. Schön, F. E. Kühn (Bayer AG), EP 1344785, 2003, CAN 139:246330.
52. H. Güterbock, Polyisobutylen und Mischpolymerisate, Springer, Berlin, 1959, pp. 77-104.
53. W. Immel in Ullmann's Enzyklopädie der Technischen Chemie, 4th ed., VCH Weinheim, 1980, 19, 216.
54. P. Börzel, K. Bronstert, F. Hovermann (BASF AG), DE 2702604, 1978; [Chem. Abstr. 1978, 89, 130182].
55. a) H.-P. Rath (BASF AG), WO 99/64482, 1999; [Chem. Abstr. 1999, 13, 23299];
56. b) J. T. Nolan, Jr., H. Chafetz (Texaco Inc.), US 3 166 546, 1965 [Chem. Abstr. 1965, 62, 44376];
57. c) J. T. Nolan Jr., H. Chafetz (Texaco Inc.), US 3 024 226, 1962; [Chem. Abstr 1962, 56, 74115];
58. d) R. E: Booth, F. E. Evans, R. E: Eibeck, M. A. Robinson (Allied Chem. Corp.), US 4227027, 1980; [Chem. Abstr. 1981, 94, 30326];
59. e) J. P. Kennedy, B. L. Goodall, A. V. Lubnin (Univerity of Akron), US 5340881, 1994; [Chem. Abstr. 1995, 122, 32399].
60. a) B. H. Lipshutz, W. Vaccuro, B. Huff, Tetrahedron Lett. 1986, 27, 4095;
61. b)H. S. Kasmai, J. Chem. Educ. 1996, 73, 830;
62. c) F. Castanellos, J. P. Fouassier, C. Priou, J. Cavezzan, J. Appl. Polym. Sci. 1996, 60, 705;
63. d) R. E. LaPointe, G. R. Roof, K. A. Abbound, J. Klosin, J. Am. Chem. Soc. 2000, 122, 9560.
64. a) J. Reedijk, A. P. Zuur, W. L. Groeneveld, Recl. Trav. Chim. Pays-Bas 1967, 86, 1127;
65. b) R. Bougon, P. Charpin, K. O. Christie, J. Isabey, M. Lance, M. Nierlich, J. Vigner, W. W. Wilson, Inorg. Chem. 1988, 27, 1389.
66. a) D. F. Shriver, S. A. Shriver, S. E. Anderson, Inorg. Chem. 1965, 4, 725;
67. b) B. I. Swanson, Inorg. Chem. 1976, 15, 253;
68. c) B. I. Swanson, J. J. Rafalko, Inorg. Chem. 1976, 15, 249;
69. d) K. R. Dunbar, R. A. Heintz, Prog. Inorg. Chem. 1997, 45, 283.
70. J. P. Kennedy, B. Ivan, Designed Polymers by Carbocationic Macromolecular Engineering, Hanser Publishers, New York, 1992, p. 103.
71. D. W. Grattan, P. H. Plesch, Makromol. Chem. 1980, 181, 751.
72. S. Garett, A. Guerrero, D. L. Hughes, M. Bochmann, Angew. Chem. 2004, 116, 2218; Angew. Chem. Int. Ed. 2004, 43, 2166.
73. S. Garett, A. Guerrero, D. L. Hughes, M. Bochmann, Angew. Chem. 2004, 116, 2218; Angew. Chem. Int. Ed. 2004, 43, 2166.
74. a) I. Puskas, E. M. Banas, A. G. Nerheim, J. Polym. Sci. 1976, 56, 191;
75. b) I. Puskas, E. M. Banas, A. G. Nerheim, G. J. Ray, Macromolecules 1979, 12, 1024;
76. c) I. Puskas, S. Meyerson, J. Org. Chem. 1984, 49, 258;
77. d) S. Nemes, J. Si, J. P. Kennedy, Polym. Bull. 1990, 23, 597;
78. e) C. Argo, S. M. Gillam, F. Orsini, Polym. Bull. 2000, 44, 71.
79. Data Collection Software for Nonius kappa-CCD devices, Delft (The Netherlands), 2001.
80. Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307ff.
81. International Tables for Crystallography, Vol. C (Ed.: A. J. C. Wilson), Kluwer Academic, Dordrecht, 1992, Tables 6.1.1.4, 4.2.6.8, 4.2.4.2.
82. G. Artus, W. Scherer, T. Priermeier, E. Herdtweck, STRUX-V A program system to handle X-Ray Data, TU München, Germany, 1997.
83. A. L. Spek, PLATON, Utrecht University, Utrecht, 2001.
84. SIR92: A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, J. Appl Crystallogr. 1994, 27, 435-436.
85. G. M. Sheldrick, SHELXL-97, Universität Göttingen, Göttingen, 1998.
86. F. Weller, H.-J. Mai, K. Dehnicke, Z. Naturforsch., B: Chem.Sci 1996, 51, 298.