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Volumn 104, Issue 9, 2000, Pages 2053-2059

Nature of Photovoltaic Action in Dye-Sensitized Solar Cells

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Indexed keywords


EID: 0347899829     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp993187t     Document Type: Article
Times cited : (696)

References (53)
  • 7
    • 0345833774 scopus 로고    scopus 로고
    • note
    • This argument for the absence of a space charge layer assumes the nanoparticles are independent of each other. As pointed out in [Kronik et al., loc. cit.] a collective space charge can exist in a sufficiently thick nanoparticulate film, if it behaves as an ensemble. While this could be so for a completely dry system, the all-pervasive contact with the electrolyte, due to the mesoporous nature of the films, will effectively decouple the particles, via screening (cf. (D) in text) and make any such effect negligible when the film is immersed in a liquid.
  • 12
    • 0347095087 scopus 로고    scopus 로고
    • note
    • Throughout this paper we give electron energies in electronvolts on the solid state scale, where electron energies are given as negative values measured from the vacuum level, which is taken as zero. To convert to the electrochemical scale, the sign has to be inverted and 4.5 eV subtracted (NHE ≈ -4.5 eV on the solid state scale).
  • 13
    • 85086352504 scopus 로고    scopus 로고
    • note
    • 3-based DSSC's (Lenzmann, Gal, Krüger, et al., to be published).
  • 28
    • 0347095085 scopus 로고    scopus 로고
    • note
    • The arguments given here are semiquantitative, with some of the limiting values deduced from measured photovoltages generated in the cell.
  • 29
    • 0347095086 scopus 로고    scopus 로고
    • note
    • Kelvin probe experiments, using a recently developed method for measurements in liquids (Bastide et al., loc. cit.) are under way to measure this shift directly.
  • 34
    • 85086353193 scopus 로고    scopus 로고
    • note
    • -3.
  • 35
    • 85086352339 scopus 로고    scopus 로고
    • note
    • 2 is known to have a large density of surface electron traps. It is possible that the photovoltage is determined by the trapping levels, rather than by the bottom of the conduction band. Also, charge transport may occur via these surface traps. This point will be considered in more detail elsewhere.
  • 49
    • 85086353827 scopus 로고    scopus 로고
    • note
    • 5, confirm this approach.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.