A Comparative Study of Claisen and Cope Rearrangements Catalyzed by Chorismate Mutase. An Insight into Enzymatic Efficiency: Transition State Stabilization or Substrate Preorganization?

Journal of the American Chemical Society

Volumn 126, Issue 1, 2004, Pages 311-319

  Marti, Sergio ^a   Andrés, Juan ^a   Moliner, Vicente ^a   Silla, Estanislao ^b   Tuñón, Iñaki ^b   Bertrán, Juan ^c  

^a UNIVERSITAT JAUME I   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

^c UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CATALYSIS; ENZYMES; FREE ENERGY; HYDROGEN BONDS; QUANTUM THEORY;

ENERGY BARRIERS; TRANSITION STATES;

ENZYME KINETICS;

CARBENE; CARBOCHORISMATE; CARBOXYLIC ACID DERIVATIVE; CHORISMATE MUTASE; CHORISMIC ACID; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; BACILLUS SUBTILIS; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CLAISEN REARRANGEMENT; COMPARATIVE STUDY; COPE REARRANGEMENT; ENZYME ACTIVE SITE; ENZYME MECHANISM; ENZYME SPECIFICITY; ENZYME SUBSTRATE COMPLEX; HYDROGEN BOND; MOLECULAR MECHANICS; QUANTUM MECHANICS;

EID: 0347129735     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0369156     Document Type: Article

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