Stereochemically Defined Osmium Centers from Asymmetric Diamination of Olefins: Mechanistic Implications for Osmium-Mediated Acrylate Functionalization

Angewandte Chemie - International Edition

Volumn 42, Issue 48, 2003, Pages 5958-5961

  Muñiz, Kilian ^a   Nieger, Martin ^a   Mansikkamäki, Heidi ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

Alkenes; Asymmetric synthesis; Osmium; Oxidation

Indexed keywords

AMINATION; OLEFINS; STEREOCHEMISTRY;

STEREOGENIC CENTERS;

OSMIUM;

ACRYLIC ACID; ALKENE; FUNCTIONAL GROUP; IMIDAZOLIDINE DERIVATIVE; OSMAIMIDAZOLIDINE; OSMIUM; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; CHEMICAL STRUCTURE; STEREOCHEMISTRY;

EID: 0346094028     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352244     Document Type: Article

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51. 2) = 0.0539, R1 = 0.0340 for I > 2σ(I). The absolute configuration was determined by refinement of Flack's x parameter, x = -0.029(5)). CCDC-213515 (6) and CCDC-213516 (7) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+ 44) 1223-336-033; or deposit@ccdc.cam.ac.uk).