Stereoselective Assembly of Three Different Carbonyl Components by Two Successive Aldol Reactions Using Group IVa and IVb Metals

Synthesis

Volumn , Issue 16, 2003, Pages 2576-2589

  Haeuseler, Andreas ^a   Henn, Wolfgang ^a   Schmittel, Michael ^a  

^a UNIVERSITY OF SIEGEN   (Germany)

Author keywords

Aldol reaction; Domino process; Enolate; Stereoselective assembly; Tin(IV)

Indexed keywords

ALDEHYDES; CARBONYLATION;

STEREOSELECTIVITY;

SYNTHESIS (CHEMICAL);

ALDEHYDE DERIVATIVE; CARBONYL DERIVATIVE; FUNCTIONAL GROUP; METAL DERIVATIVE; TETRAHYDROPYRAN DERIVATIVE; TIN DERIVATIVE; TRANSITION ELEMENT;

ALDOL REACTION; CHEMICAL STRUCTURE; ORGANIC CHEMISTRY; PHASE TRANSITION; REACTION ANALYSIS; REVIEW; STEREOCHEMISTRY; STEREOISOMERISM; STRUCTURE ANALYSIS;

EID: 0345305252     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-42450     Document Type: Review

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22. Aldol reaction as second step in a domino process: (a) Arai, T.; Sasai, H.; Aoe, K.; Okamura, K.; Date, T.; Shibasaki, M. Angew. Chem., Int. Ed. Engl. 1996, 35, 104. (b) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; De Vries, A. H. M. Angew. Chem. Int. Ed. 1997, 36, 2620. (c) Ono, M.; Nishimura, K.; Nagaoka, Y.; Tomioka, K. Tetrahedron Lett. 1999, 40, 1509. (d) Huang, X.; Xie, M. H. Org. Lett. 2002, 4, 1331. (e) Langer, P.; Saleh, N. N. R.; Freifeld, I. Chem. Commun. 2002, 168. (f) Bilodeau, F.; Dube, L.; Deslongchamps, D. Tetrahedron 2003, 59, 2781. (g) Cauble, D. F.; Gipson, J. D.; Krische, M. J. J. Am. Chem. Soc. 2003, 125, 1110.
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