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For a review: (a) Yoon, K. B. Chem. Rev. 1993, 93, 321. Examples of advantageous use of molecular sieves in organic reactions: (b) Hanson, R. M.; Sharpless, K. B. J. Org. Chem. 1986, 51, 1922. (c) Narasaka, K.; Inoue, M.; Yamada, T. Chem. Lett. 1986, 1967. (d) Mikami, K.; Terada, M.; Nakai, T. J. Am. Chem. Soc. 1989, 111, 1940. Meerwein-Ponndorf-Verley reduction of aldehydes by using samarium(III) alkoxides and molecular sieves: (e) Ding, Z.-B.; Wu. S.-H. Huaxue Xuebao 1997, 55, 351. (f) Ding, Z.-B.; Cheng, K.-J.; Wu. S.-H. Huaxue Xuebao 1997, 55, 1030.
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3 or NaI for dehalogenation of α-chloroketones: (a) Gemal, A. L.; Luche, J. L. Tetrahedron Lett. 1980, 21, 3195. (b) Fukuzawa, S.i.; Tsuruta, T.; Fujinami, T.; Sakai, S. J. Chem. Soc., Perkin Trans. 1 1987, 1473.
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Gemal, A.L.1
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53
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37049081924
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For compound 53c: (a) Yamamoto, K.; Ando, H.; Chikamatsu, H. J. Chem. Soc., Chem. Commun. 1987, 334. (b) Corey, E. J.; Chen. Z. Tetrahedron Lett. 1994, 35, 8731. For compound 55c: see ref 7b. For compounds 67c and 68c: (c) Thompson, S. H. J.; Mahon, M. F.; Molloy, K. C.; Hadley, M. S.; Gallagher, T. J. Chem. Soc., Perkin Trans. 1 1995, 379.
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Examples of related reactions: (a) Oku, A.; Harada, T.; Kita, K. Tetrahedron Lett. 1982, 681. (b) Yu, Y.; Zhang, Y.; Ling, R. Synth. Commun. 1993, 23, 1973.
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Pirrung, M.C.4
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For related studies: (a) Majewski, M.; Gleave, D. M. Tetrahedron Lett. 1989, 30, 5681. (b) Juaristi, E.; Beck, A. K.; Hansen, J.; Matt, T.; Mukhopadhyay, T.; Simson, M.; Seebach, D. Synthesis 1993, 1271. (c) Ranu, B. C.; Chakreborty, R. Tetrahedron 1993, 49, 5333. (d) Kobayashi, S.; Hachiya, I. J. Org. Chem. 1994, 59, 3590. Uncatalyzed aldol reaction of (trichlorosilyl)oxycyclohexene with benzaldehyde may undergo a boatlike transition state to give predominantly a syn-aldol product. See: (e) Denmark, S. E.; Wong, K.-T.; Stavenger, R. A. J. Am. Chem. Soc. 1997, 119, 2333.
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For related studies: (a) Majewski, M.; Gleave, D. M. Tetrahedron Lett. 1989, 30, 5681. (b) Juaristi, E.; Beck, A. K.; Hansen, J.; Matt, T.; Mukhopadhyay, T.; Simson, M.; Seebach, D. Synthesis 1993, 1271. (c) Ranu, B. C.; Chakreborty, R. Tetrahedron 1993, 49, 5333. (d) Kobayashi, S.; Hachiya, I. J. Org. Chem. 1994, 59, 3590. Uncatalyzed aldol reaction of (trichlorosilyl)oxycyclohexene with benzaldehyde may undergo a boatlike transition state to give predominantly a syn-aldol product. See: (e) Denmark, S. E.; Wong, K.-T.; Stavenger, R. A. J. Am. Chem. Soc. 1997, 119, 2333.
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Juaristi, E.1
Beck, A.K.2
Hansen, J.3
Matt, T.4
Mukhopadhyay, T.5
Simson, M.6
Seebach, D.7
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64
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For related studies: (a) Majewski, M.; Gleave, D. M. Tetrahedron Lett. 1989, 30, 5681. (b) Juaristi, E.; Beck, A. K.; Hansen, J.; Matt, T.; Mukhopadhyay, T.; Simson, M.; Seebach, D. Synthesis 1993, 1271. (c) Ranu, B. C.; Chakreborty, R. Tetrahedron 1993, 49, 5333. (d) Kobayashi, S.; Hachiya, I. J. Org. Chem. 1994, 59, 3590. Uncatalyzed aldol reaction of (trichlorosilyl)oxycyclohexene with benzaldehyde may undergo a boatlike transition state to give predominantly a syn-aldol product. See: (e) Denmark, S. E.; Wong, K.-T.; Stavenger, R. A. J. Am. Chem. Soc. 1997, 119, 2333.
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Chakreborty, R.2
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For related studies: (a) Majewski, M.; Gleave, D. M. Tetrahedron Lett. 1989, 30, 5681. (b) Juaristi, E.; Beck, A. K.; Hansen, J.; Matt, T.; Mukhopadhyay, T.; Simson, M.; Seebach, D. Synthesis 1993, 1271. (c) Ranu, B. C.; Chakreborty, R. Tetrahedron 1993, 49, 5333. (d) Kobayashi, S.; Hachiya, I. J. Org. Chem. 1994, 59, 3590. Uncatalyzed aldol reaction of (trichlorosilyl)oxycyclohexene with benzaldehyde may undergo a boatlike transition state to give predominantly a syn-aldol product. See: (e) Denmark, S. E.; Wong, K.-T.; Stavenger, R. A. J. Am. Chem. Soc. 1997, 119, 2333.
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Wong, K.-T.2
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