Catalytic TMSCl promoted powerful aldol addition and Claisen condensation mediated by TiCl4/Bu3N agent: Comparison and evaluation with the Mukaiyama aldol addition

Tetrahedron Letters

Volumn 40, Issue 22, 1999, Pages 4227-4230

  Yoshida, Yoshihiro ^a   Matsumoto, Noriaki ^a   Hamasaki, Ryota ^a   Tanabe, Yoo ^a  

^a KWANSEI GAKUIN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ESTER DERIVATIVE; KETONE DERIVATIVE; TITANIUM DERIVATIVE; TRIMETHYLSILYL DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CROSS REACTION; SYNTHESIS; THERMOSTABILITY;

EID: 0033612353     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00682-6     Document Type: Article

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27. 1H NMR (400 MHz) [syn-isomer] δ 0.21 (9H, s), 5.22 (1H, d, J = 8.0 Hz), 5.26 (1H, d, J = 8.0 Hz), 7.22-7.99 (10H, m); [anti-isomer] δ -0.15 (9H, s), 5.08 (1H, d, J = 9.2 Hz), 5.16 (1H, d, J = 9.2 Hz), 7.22-7.99 (10H, m).
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