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Volumn 5, Issue , 2003, Pages 190-199

New architectures from the self-assembly of MIISO4 salts with bis(4-pyridyl) ligands. The first case of polycatenation involving three distinct sets of 2D polymeric (4,4)-layers parallel to a common axis

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM SULFATE; COBALT COMPLEX; COORDINATION COMPOUND; COPPER COMPLEX; METAL COMPLEX; POLYMER; SULFATE;

EID: 0345295675     PISSN: 14668033     EISSN: None     Source Type: Journal    
DOI: 10.1039/b304201d     Document Type: Article
Times cited : (96)

References (54)
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    • note
    • 22a and has the meaning of counting the total number (finite) of distinct nets (as, for instance, in the case of an n-fold diamondoid net). In polycatenated systems we cannot define a degree of interpenetration with the same topological meaning as described above. Indeed, in the inclined interweaving of 2D layers (2D → 3D) there is an infinite number of other motifs interlocked with each single motif, and to simply describe such arrays as 'n-fold interpenetrated networks' seems to us rather inadequate. Also, in the case of parallel interweaving of 2D layers (2D → 3D) we prefer to state, for instance, that a layer is catenated to other two (one 'upper' and one 'lower' , with a 'density of catenation' equal to 2) rather than to define the system as 3-fold interpenetrated (that seems rather misleading and can be confused with a real case of a 3-fold interpenetration of three layers located on a common average plane). Different systems with peculiar topologies can need different notations.


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