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There is a renewed interest within the scientific community for the enumeration/classification of three-dimensional networks (see e.g.: U. Müller, Angen: Chem., Int. Ed., 2000, 39, 502 and refs. therein; O. Delgado Friedrichs, A. W. M. Dress, D. H. Huson, K. Klinowski and A. L. Mackay, Nature (London), 1999, 400, 644). There are, at present, different approaches and notations, including those of the older works by Wells (see réf. 8) and of the more recent contributions by O'Keeffe (see refs. 10 and 17), that still need to be integrated. We are currently using the O'KeeffeAVells notation with Schläfli symbols.
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2000,122,4044. In this case the self-entangled frame is not based exclusively on coordinative bonds but arises from the interactions of the anions connecting the ladders. Obviously, this example can be generalized since any -fold interpenetrated motif can give rise to a unique selfentangled array by joining the independent frames with bridging groups.
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M. A. Withersby, A. J. Blake, N. R. Champness, P. A. Cooke, P. Hubberstey and M. Schröder, J. Am. Chem. Soc., 2000,122,4044. In this case the self-entangled frame is not based exclusively on coordinative bonds but arises from the interactions of the anions connecting the ladders. Obviously, this example can be generalized since any -fold interpenetrated motif can give rise to a unique selfentangled array by joining the independent frames with bridging groups.
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33746970002
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2i (no. 4), a = 8.634(2), 6=16.043(3), c = 22.164(4) A; = 91.42(2)°, V= 3069.1(11) A3, Z = 4. L. Carlucci, G. Ciani, D. M. Proserpio and S. Rizzato, unpublished results.
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Crystal data for [Ag2(2-ethpyz)3][SbF6]2: monoclinic, space group P2i (no. 4), a = 8.634(2), 6=16.043(3), c = 22.164(4) A; = 91.42(2)°, V= 3069.1(11) A3, Z = 4. L. Carlucci, G. Ciani, D. M. Proserpio and S. Rizzato, unpublished results.
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33746980402
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2, with a = 9.406(3), b = 9.501(2), c = 10.084(3) A, a = 62.11(2), =89.19(3), y = 73.05(2)°, K= 753.9(4) A', Z = 2. L. Carlucci, G. Ciani, D. M. Proserpio and S. Rizzato, unpublished results
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Crystal data for [Cu(bpe)(SO4)]-H2O: triclinic, space group PI (no. 2), with a = 9.406(3), b = 9.501(2), c = 10.084(3) A, a = 62.11(2), =89.19(3), y = 73.05(2)°, K= 753.9(4) A', Z = 2. L. Carlucci, G. Ciani, D. M. Proserpio and S. Rizzato, unpublished results.
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38
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0030956645
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Angew. Chem., Int. Ed.EngI.
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39
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33747013461
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1999, 38,3641.
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A recent report of synthetic zeolite-like networks with doublecrankshaft subunits, exhibiting the gismondine and a pseudofeldspar [(4',62,8)(42,61,8)] topology can be found in: R. Kniep, G. Schäfer, H. Engelhardt and I. Boy, Angcw. Chem., Int. Ed., 1999, 38,3641.
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33746970500
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Taking into account also the sulfates the overall array must be described as a self-interpenetrated 6-connected network of very complex topology.
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Taking into account also the sulfates the overall array must be described as a self-interpenetrated 6-connected network of very complex topology.
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44
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0028881975
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1999. The graphic representation of the surfaces of the cavities was obtained with SURFNET: R. A. Laskowski, J.MoI. Graph., 1995, 13,323.
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An analysis of the holes was performed with the PLATON program: A. L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University, 1999. The graphic representation of the surfaces of the cavities was obtained with SURFNET: R. A. Laskowski, J.MoI. Graph., 1995, 13,323.
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PLATON, a Multipurpose Crystallographic Tool, Utrecht University
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