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4, 50 mM, 1 mL) is quickly injected into an aqueous solution of AgNO3 (0.1 mM, 100 mL) and sodium citrate (0.3 mM). Bis(p-sulfonatophenyl)-phenylphosphine (2 mL, 5 mM) is subsequently added as a particle protecting agent. We have also used poly(vinylpyrrolidone) (mw ∼ 10 000, 1 mL, 5 g/L) as a protecting agent, with essentially the same results.
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