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Volumn 5, Issue 4, 1999, Pages 1176-1185

Reactions of bare FeO+ with element hydrides EH(n) (E = C, N, O, F, Si, P, S, Cl)

Author keywords

Gas phase chemist; Hydrides; Iron oxide; Mass spectrometry; Oxidation

Indexed keywords

IRON OXIDE;

EID: 0242660229     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3765(19990401)5:4<1176::aid-chem1176>3.0.co;2-2     Document Type: Article
Times cited : (62)

References (72)
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    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 1973
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    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1420
  • 14
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    • note
    • -1, enables a rapid dehydrogenation of water.
  • 17
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    • (Ed.: B. Freiser), Kluwer Academic Publishers, Dordrecht
    • b) data for iron compounds are from: Organometallic Ion Chemistry (Ed.: B. Freiser), Kluwer Academic Publishers, Dordrecht, 1996, p. 283;
    • (1996) Organometallic Ion Chemistry , pp. 283
  • 20
    • 0345386288 scopus 로고    scopus 로고
    • note
    • The branching ratios vary, depending on the method used (see ref. [12]), and the data given in the present paper are those in ref. [12] obtained by FT-ICR.
  • 34
    • 33748232726 scopus 로고
    • O. Blum, D. Stöckigt, D. Schröder, H. Schwarz, Angew. Chem. 1992. 104, 637; Angew. Chem. Int. Ed. Engl. 1992, 31, 603.
    • (1992) Angew. Chem. Int. Ed. Engl. , vol.31 , pp. 603
  • 36
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    • note
    • 18O exchange was observed for oxidized iron porphyrin complexes (Por)FeO. However, the exchange is suppressed completely if the sixth coordination site of iron is blocked, for example, by an axial imidazole ligand (ref. [19]).
  • 37
    • 0344523972 scopus 로고    scopus 로고
    • note
    • The difference between our previous (φ = 0.5) value and the present one (φ = 0.18) for the efficiency of reaction (4) can be attributed by and large to the use of a new scheme for calibration of rate constants (see ref. [12]), and of the more appropriate capture theory for calculation of the gas kinetic collision rates (ref. [16]).
  • 38
    • 85088333377 scopus 로고    scopus 로고
    • note
    • + cannot be included, because this ion is the mass-selected reactant.
  • 39
    • 85088332329 scopus 로고    scopus 로고
    • note
    • D < 2.
  • 41
    • 85088332817 scopus 로고    scopus 로고
    • note
    • 5A' ground state (ref. 15c).
  • 45
    • 4244014631 scopus 로고
    • Ph.D. Thesis. Technische Universität Berlin, D83
    • D. Schröder. Ph.D. Thesis. Technische Universität Berlin, D83, 1992.
    • (1992)
    • Schröder, D.1
  • 51
    • 0000633651 scopus 로고
    • nO spcies (n = 0-4) were adopted from theoretical studies using the G2 approach; see: a) C. L. Darling, H. B. Schlegel, J. Phys. Chem. 1993, 97, 8207;
    • (1993) J. Phys. Chem. , vol.97 , pp. 8207
    • Darling, C.L.1    Schlegel, H.B.2
  • 54
    • 0344954762 scopus 로고    scopus 로고
    • note
    • Both are G2 values from ref. [34a] and ref. [34b], respectively. Note that the calculated total energies at the G2 level are identical, and the minor difference is probably due to the conversion to absolute heats of formation.
  • 57
    • 0344092739 scopus 로고    scopus 로고
    • note
    • -1.
  • 68
    • 85088333461 scopus 로고    scopus 로고
    • note
    • 4: for a discussion, see ref. [12].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.