Quantitative trace element analysis of single fluid inclusions by proton-induced X-ray emission (PIXE): Application to fluid inclusions in hydrothermal quartz

Geochimica et Cosmochimica Acta

Volumn 67, Issue 22, 2003, Pages 4337-4352

  Kurosawa, Masanori ^a   Shimano, Sadayoshi ^a   Ishii, Satoshi ^a   Shima, Kunihiro ^a   Kato, Takumi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL COMPOSITION; FLUID INCLUSION; HYDROTHERMAL DEPOSIT; QUARTZ; TRACE ELEMENT;

EID: 0242624793     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(03)00378-8     Document Type: Article

References (46)

1. Ando A. (1964) Geochemistry of germanium in the metallic sulfide ore deposits in Japan. Rep. Geol. Surv. Japan 208, 72 p. (in Japanese with English abstract)
2. 2O loss from fluid inclusions in natural quartz crystal Contrib. Mineral. Petrol. 137 1999 1-14
3. Audétat A.Günther D.Heinrich C.A.Formation of a magmatic-hydrothermal ore deposit: Insights with LA-ICP-MS analysis of fluid inclusions Science 279 1998 2091-2094
4. Audétat A.Günther D.Heinrich C.A.Causes for large-scale metal zonation around mineralized plutons: Fluid inclusion LA-ICP-MS evidence from the Mole granite, Australia Econ. Geol. 95 2000 1563-1581
5. Audétat A.Günther D.Heinrich C.A.Magmatic hydrothermal evolution in a fractionating granite: A microchemical study of the Sn-W-F-mineralized Mole granite Geochim. Cosmochim. Acta 64 2000 3373-3393
6. Ballhaus C.Ryan C.G.Mernagh T.P.Green D.H.The partitioning of Fe, Ni, Cu, Pt, and Au between sulfide, metal, and fluid phases: A pilot study Geochim. Cosmochim. Acta 58 1994 811-826
7. Berger M. J., Hubbell J. H. (1987) NBSIR 87-3597. National Institute of Standards and Technology, Gaithersburg, MD
8. Bernstein L.R.Germanium geochemistry and mineralogy Geochim. Cosmochim. Acta 49 1985 2409-2422
9. Campbell J.L.Instrumentation, fundamentals, and quantification Johansson S.A.E. Campbell J.L. Malmqvist K.G. Particle-Induced X-ray Emission Spectrometry (PIXE) 1995 19-100 John WileyNew York
10. Cohen D.D.Harrigan M.K- and L-shell ionization cross sections for protons and helium ions calculated in the ECPSSR theory At. Data Nucl. Data Tables. 33 1985 255-343
11. Czamanske G.K.Sisson T.W.Campbell J.L.Teesdale W.J.Micro-PIXE analysis of silicate reference standards Am. Mineral. 78 1993 893-903
12. Damman A.H.Kars S.M.Touret J.L.R.Rieffe E.C.Kramer J.A.L.M.Vis R.D.Pintea I.PIXE and SEM analyses of fluid inclusions in quartz crystals from the K-alteration zone of the Rosia Poieni porphyry-Cu deposit, Apuseni Mountains, Rumania Eur. J. Mineral. 8 1996 1081-1096
13. Frantz J.D.Mao H.K.Zhang Y.-G.Wu Y.Thompson A.C.Underwood J.H.Giauque R.D.Jones K.W.Rivers M.L.Analysis of fluid inclusions by X-ray fluorescence using synchrotron radiation Chem. Geol. 69 1988 235-244
14. Frondel C. (1962) Quartz. In The System of Mineralogy, 7th ed., Vol. III, Silica Minerals, pp. 9-250. John Wiley, New York
15. Götze J.Tichomirowa M.Fuchs H.Pilot J.Sharp Z.D.Geochemistry of agates: A trace element and stable isotope study Chem. Geol. 175 2001 523-541
16. Günther D.Audétat A.Frischknecht R.Heinrich C.A.Quantitative analysis of major, minor and trace elements in fluid inclusions using laser ablation inductively coupled plasma mass spectrometry J. Anal. Atom. Spectrom. 13 1998 263-270
17. Heinrich C.A.Ryan C.G.Mernagh T.P.Eadington P.J.Segregation of ore metals between magmatic brine and vapor: A fluid inclusion study using PIXE microanalysis Econ. Geol. 87 1992 1566-1583
18. Horn I.Hinton R.W.Jackson S.E.Longerich H.P.Ultra-trace element analysis of NIST SRM 616 and 614 using laser-ablation microprobe- inductively coupled plasma- mass spectrometry (LAM-ICP-MS): A comparison with secondary ion mass spectrometry (SIMS) Geostand. Newsl. 21 1997 191-203
19. International Commission on Radiation Units and Measurements Stopping powers and ranges for protons and alpha particles ICRU Rep 49 1993 117-180
20. Jackson S.E.Longerich H.P.Dunning G.R.Fryer B.J.The application of laser-ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS) to in situ trace element determinations in minerals Can. Mineral. 30 1992 1049-1064
21. Kurosawa M.Sueno S.Shima K.Ohshima H.Ishii S.Kamiya H.Kimoto S.Ohyi H.Hayashi K.Development of a new sample chamber for proton microprobe analysis of mineral samples Nucl. Instrum. Methods Phys. Res. B142 1998 599-605
22. Kurosawa M.Campbell J.L.Teesdale W.J.Ohyi H.Deguchi Y.Murao S.Quantitative trace element analyses of silicate reference materials and a stainless steel using the proton microprobe Chem. Geol. 160 1999 241-250
23. Mavrogenes J.A.Bodnar R.J.Anderson A.J.Bajt S.Sutton S.R.Rivers M.L.Assessment of the uncertainties and limitations of quantitative elemental analysis of individual fluid inclusions using synchrotron X-ray fluorescence (SXRF) Geochim. Cosmochim. Acta 59 1995 3987-3995
24. Maxwell J.A.Campbell J.L.Teesdale W.J.The Guelph PIXE software package Nucl. Instrum. Methods Phys. Res. B43 1989 218-230
25. Maxwell J.A.Teesdale W.J.Campbell J.L.The Guelph PIXE software package II Nucl. Instrum. Methods Phys. Res. B95 1995 407-421
26. McCandless T.E.Lajack D.J.Ruiz J.Ghazi A.M.Trace element determination of single fluid inclusions in quartz by laser ablation ICP-MS Geostand. Newsl. 21 1997 279-287
27. Ménez B.Philippot P.Bonnin-Mosbah M.Gibert F.Fluid inclusion depth and thickness estimates using Na nuclear reaction resonance and Si elastic scattering Nucl. Instrum. Methods Phys. Res. B158 1999 533-537
28. Ménez B.Philippot P.Bonnin-Mosbah M.Simionovici A.Gibert F.Analysis of individual fluid inclusions using Synchrotron X-ray Fluorescence microprobe: Progress toward calibration for trace element Geochim. Cosmochim. Acta 66 2002 561-576
29. Mosbah M.Clocchiatti R.Michaud V.Piccot D.Chevallier P.Legrand F.Als Nilsen G.Grübel G.Micro PIXE and micro SXRF: Comparison of the two methods and application to glass inclusions from volcano (Eolian Islands-Italy) Nucl. Instrum. Methods Phys. Res. B104 1995 481-488
30. Paul H.Sacher J.Fitted empirical reference cross sections for K-shell ionization by proton At. Data Nucl. Data Tables 42 1989 105-156
31. Philippot P.Ménez B.Chevallier P.Gibert F.Legrand F.Populus P.Absorption correction procedures for quantitative analysis of fluid inclusions using synchrotron radiation X-ray fluorescence Chem. Geol. 144 1998 121-136
32. Philippot P.Ménez B.Drakopoulos M.Simionovici A.Snigirev A.Snigireva I.Mapping trace-metal (Cu, Zn, As) distribution in a single fluid inclusion using a third generation synchrotron light source Chem. Geol. 173 2001 151-158
33. Rankin A.H.Ramsey M.H.Coles B.Van Langevelde F.Thomas C.R.The composition of hypersaline, iron-rich granitic fluids based on laser-ICP and synchrotron-XRF microprobe analysis of individual fluid inclusions in topaz, Mole granite, eastern Australia Geochim. Cosmochim. Acta 56 1992 67-79
34. Reuter W.Lurio A.Cardone F.Ziegler J.F.Quantitative analysis of complex targets by proton-induced x rays J. Appl. Phys. 46 1975 3194-3202
35. Ryan C.G.Advances in fluid inclusion analysis using the nuclear microprobe Nucl. Instrum. Methods Phys. Res. B158 1999 523-532
36. Ryan C.G.Cousens D.R.Sie S.H.Griffin W.L.Suter G.F.Quantitative PIXE microanalysis of geological material using the CSIRO proton microprobe Nucl. Instrum. Methods Phys. Res. B47 1990 55-71
37. Ryan C.G.Cousens D.R.Heinrich C.A.Griffin W.L.Sie S.H.Mernagh T.P.Quantitative PIXE microanalysis of fluid inclusions based on a layered yield model Nucl. Instrum. Methods Phys. Res. B54 1991 292-297
38. Ryan C.G.Heinrich C.A.Mernagh T.P.PIXE microanalysis of fluid inclusions and its application to study ore metal segregation between magmatic brine and vapor Nucl. Instrum. Meth. Phys. Res. B77 1993 463-471
39. Ryan C.G.Heinrich C.A.van Achterbergh E.Ballhaus C.Mernagh T.P.Microanalysis of ore-forming fluids using the scanning proton microprobe Nucl. Instrum. Methods Phys. Res. B104 1995 182-190
40. Shepherd T.J.Chenery S.R.Laser ablation ICP-MS elemental analysis of individual fluid inclusions: An evaluation study Geochim. Cosmochim. Acta 59 1995 3997-4007
41. 2O under vapor-saturated conditions Geochim. Cosmochim. Acta 52 1988 989-1005
42. Ulrich T.Günther D.Heinrich C.A.Gold concentrations of magmatic brines and the metal budget of porphyry copper deposits Nature 399 1999 676-679
43. Vanko D.A.Sutton S.R.Rivers M.L.Bodnar R.J.Major-element ratios in synthetic fluid inclusions by synchrotron X-ray fluorescence microprobe Chem. Geol. 109 1993 125-134
44. Vanko D.A.Bonnin-Mosbah M.Philippot P.Roedder E.Sutton S.R.Fluid inclusion in quartz from oceanic hydrothermal specimens and the Bingham, Utah porphyry-Cu deposit: A study with PIXE and SXRFM Chem. Geol. 173 2001 227-238
45. Weil J.A.A review of electron spin spectroscopy and its application to the study of paramagnetic defects in crystalline quartz Phys. Chem. Minerals 10 1984 149-165
46. Weise G.Schrön W.Uschmann W.Spurenelementgehalte in Bergkristtallen ("Tiefengrubener Diamanten") bei Bad Berka (Thüringen) N. Jb. Miner. Mh. 1993 1993 363-373