Asymmetric Cleavage of Racemic 1,3-Oxazolidines - A New Dynamic Process in Homogeneous Rh(I)-Catalyzed Hydrogenation

Advanced Synthesis and Catalysis

Volumn 345, Issue 1-2, 2003, Pages 239-245

  Tararov, Vitali I ^a   Kadyrov, Renat ^b   Monsees, Axel ^b   Riermeier, Thomas H ^b   Börner, Armin ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b EVONIK INDUSTRIES AG   (Germany)

Author keywords

Enantioselective hydrogenation; Homogeneous catalysis; P ligands; Phosphanes; Rhodium

Indexed keywords

(6,6' DIMETHOXYBIPHENYL 2,2' DIYL)BIS(DI 4 TOLYLPHOSPHANE); 1 BENZYL 3,4 BIS(DIPHENYLPHOSPHANYL)PYRROLIDINE; 1 [2 (DICYCLOHEXYLPHOSPHANYL)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHANE; 1 [2 (DICYCLOHEXYLPHOSPHANYL)FERROCENYL]ETHYLDIPHENYLPHOSPHANE; 1 [2 (DIPHENYLPHOSPHANYL)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHANE; 1 [2' (DIPHENYLPHOSPHANYL)PHENYL]DIPHENYLPHOSPHANYLETHANE; 1,2 BIS(2,5 DIETHYLPHOSPHOLANO)ETHANE; 1,2 BIS(2,5 DIETHYLPHOSPHOLANYL)BENZENE; 1,2 BIS(2,5 DIMETHYLPHOSPHOLANYL)BENZENE; 1,2 BIS(2,5 DIMETHYLPHOSPHOLANYL)ETHANE; 1,2 BIS(DIPHENYLPHOSPHANYL)PROPANE; 2,2' BIS(DI 4 TOLYLPHOSPHANYL) 1,1' BINAPHTHYL; 2,2' BIS(DIPHENYLPHOSPHANYL) 1,1' BINAPHTHYL; 2,3 BIS(DIPHENYLPHOSPHANYL)BICYCLO[2.2.1]HEPT 5 ENE; AMINE; BIS(DIPHENYLPHOSPHANYL)BUTANE; BIS(DIPHENYLPHOSPHANYL)PENTANE; BIS(METHYLPHENYLPHOSPHANYL)BENZENE; BIS[(2 METHOXYPHENYL)PHENYLPHOSPHANYL]ETHANE; CATION; ETHYLAMINE; HYDROGEN; HYDROXYL GROUP; IMINE; LIGAND; OXAZOLIDINE DERIVATIVE; RHODIUM; RHODIUM COMPLEX; SOLVENT; UNCLASSIFIED DRUG; [(3,4 DIMETHYLPHOSPHAFERROCEN 2 YL)METHYL]DICYCLOHEXYLPHOSPHANE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHIRALITY; DYNAMICS; HYDROGENATION; OBSERVATION; PRESSURE; STEREOCHEMISTRY; TEMPERATURE;

EID: 0242523114     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200390018     Document Type: Article

References (31)

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31. Since the parallel screening is known as a methodology giving only preliminary hits also other ligands might be useful. However, is was not possible to identify them under our high-throughput conditions.