Synthesis and characterization of enolato-cobalt and -nickel complexes bearing TpiPr2 ligand, [TpiPr2M(XCHY)]n [TpiPr2=hydrotris(3,5-diisopropylpyrazolyl)borato; n=1, 2], obtained from hydroxometal complexes, (μ-OH)2(MTpiPr2) 2, and active methylene compounds, CH2XY

Inorganica Chimica Acta

Volumn 350, Issue , 2003, Pages 163-174

  Kujime, Masato ^a   Hikichi, Shiro ^a,b   Akita, Munetaka ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

Enolato cobalt complexes; Enolato nickel complexes; Hydroxometal complexes; Methylene compounds

Indexed keywords

CHELATION; COBALT COMPOUNDS; CONDENSATION; DRYING; ESTERS; HYDROLYSIS; LIGANDS; NICKEL COMPOUNDS; PRASEODYMIUM COMPOUNDS; SODIUM SULFATE; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY; X RAY ANALYSIS; X RAY CRYSTALLOGRAPHY; X RAYS;

ACTIVE METHYLENE COMPOUNDS; CHELATED STRUCTURES; COBALT COMPLEXES; DEHYDRATIVE CONDENSATION; HYDROXOMETAL COMPLEXES; METHYLENE COMPOUNDS; NICKEL COMPLEX; SYNTHESIS AND CHARACTERIZATIONS;

SULFUR COMPOUNDS;

5,5 DIMETHYL 1,3 CYCLOHEXANEDIONE; ACETIC ACID DERIVATIVE; BENZALDEHYDE; CARBENOID; CARBOXYL GROUP; COBALT COMPLEX; DESICCANT; DIMER; ESTER DERIVATIVE; MONOMER; NICKEL COMPLEX; PYRAZOLE DERIVATIVE;

ARTICLE; CHELATION; CHEMICAL BINDING; CRYSTAL STRUCTURE; HYDROLYSIS; ISOMERISM; POLYMERIZATION; STEREOSPECIFICITY; STRUCTURE ANALYSIS; THERMODYNAMICS; THERMOSTABILITY; X RAY CRYSTALLOGRAPHY;

EID: 0142248996     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01547-5     Document Type: Article

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