Synthesis and characterization of coordinatively unsaturated alkynyl- and aryl-cobalt complexes with 15 valence electrons, TpiPr2Co-R, bearing the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (TpiPr2)

Organometallics

Volumn 21, Issue 18, 2002, Pages 3762-3773

  Yoshimitsu, Shin Ichi ^a   Hikichi, Shiro ^a,b   Akita, Munetaka ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CONDENSATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ELECTRONS; MOISTURE; SYNTHESIS (CHEMICAL);

VALENCE ELECTRONS;

COMPLEXATION;

EID: 0013022712     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020268u     Document Type: Article

References (96)

1. Yamamoto, A. Organotransition Metal Chemistry; Wiley-Interscience: New York, 1986. Collman, J. P.; Hegedus, L. S.; Norton, J. H.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science Books: Mill Valley, 1987. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley-Interscience: New York, 2001. Cornils, B.; Herrmann, W. Applied Homogeneous Catalysis with Organometallic Compounds (2 vols.); VCH: Oxford, 1996, Abel, E. W.; Stone, F. G. A.; Wilkinson, G. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995.
2. Yamamoto, A. Organotransition Metal Chemistry; Wiley-Interscience: New York, 1986. Collman, J. P.; Hegedus, L. S.; Norton, J. H.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science Books: Mill Valley, 1987. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley-Interscience: New York, 2001. Cornils, B.; Herrmann, W. Applied Homogeneous Catalysis with Organometallic Compounds (2 vols.); VCH: Oxford, 1996, Abel, E. W.; Stone, F. G. A.; Wilkinson, G. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995.
3. Yamamoto, A. Organotransition Metal Chemistry; Wiley-Interscience: New York, 1986. Collman, J. P.; Hegedus, L. S.; Norton, J. H.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science Books: Mill Valley, 1987. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley-Interscience: New York, 2001. Cornils, B.; Herrmann, W. Applied Homogeneous Catalysis with Organometallic Compounds (2 vols.); VCH: Oxford, 1996, Abel, E. W.; Stone, F. G. A.; Wilkinson, G. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995.
4. Yamamoto, A. Organotransition Metal Chemistry; Wiley-Interscience: New York, 1986. Collman, J. P.; Hegedus, L. S.; Norton, J. H.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science Books: Mill Valley, 1987. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley-Interscience: New York, 2001. Cornils, B.; Herrmann, W. Applied Homogeneous Catalysis with Organometallic Compounds (2 vols.); VCH: Oxford, 1996, Abel, E. W.; Stone, F. G. A.; Wilkinson, G. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995.
5. Yamamoto, A. Organotransition Metal Chemistry; Wiley-Interscience: New York, 1986. Collman, J. P.; Hegedus, L. S.; Norton, J. H.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science Books: Mill Valley, 1987. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley-Interscience: New York, 2001. Cornils, B.; Herrmann, W. Applied Homogeneous Catalysis with Organometallic Compounds (2 vols.); VCH: Oxford, 1996, Abel, E. W.; Stone, F. G. A.; Wilkinson, G. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995.
6. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
7. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
8. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
9. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
10. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
11. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
12. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
13. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
14. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
15. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
16. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
17. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
18. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
19. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
20. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
21. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
22. Examples of Mn, Co, and Fe complexes: Mn: Howard, C. G.; Girolami, G. S.; Wilkinson, G.; Thornton-Pett, M.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1983, 2631. Buttrus, N. H.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D.; Sullivan, A. C. J. Chem. Soc., Chem. Commun. 1985, 1380. C: Morris, R. J.; Gilorami, G. S. Organometallics 1989, 8, 1478. Wehmschulte, R.; Power, P. P. Organometallics 1995, 14, 3264. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fe: Chatt, J.; Shaw, B. L. J. Chem. Soc. 1961, 285. Hermes, A. R.; Girolami, G. S. Organometallics 1987, 6, 763. Müller, H.; Seidel, W.; Görls, H. J. Organomet. Chem. 1992, 445, 133. Müller, H.; Seidel, W.; Görls, H. Angew. Chem., Int. Ed. Engl. 1995, 34, 325. Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123. Leung, W.-P.; Lee, H. K.; Weng, L.-H.; Luo, B-S.; Zhou, Z.-Y.; Mak, T. W. C. Organometallics 1996, 15, 1785. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Jr. Organometallics 1998, 17, 2313. Co: Theopold, K. H.; Silvestre, J.; Byrne, E. K.; Richeson, D. S. Organo-metallics 1989, 8, 2001. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain, B.; Hursthouse, M. B. Polyhedron 1990, 9, 931. Hursthouse, M. B.; Izod, K. J.; Motevalli, M.; Thornton, P. Polyhedron 1996, 15, 135. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126.
23. Akita, M.; Shirasawa, N.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 973. Shirasawa, N.; Akita, M.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1999, 417. Shirasawa, N.; Nguyet, T. T.; Hikichi, S.; Moro-oka, Y. Akita, M. Organometallics 2001, 20, 3582. See also: Uehara, K.; Hikichi, S.; Akita, M. Organometallics 2001, 20, 5002.
24. Akita, M.; Shirasawa, N.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 973. Shirasawa, N.; Akita, M.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1999, 417. Shirasawa, N.; Nguyet, T. T.; Hikichi, S.; Moro-oka, Y. Akita, M. Organometallics 2001, 20, 3582. See also: Uehara, K.; Hikichi, S.; Akita, M. Organometallics 2001, 20, 5002.
25. Akita, M.; Shirasawa, N.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 973. Shirasawa, N.; Akita, M.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1999, 417. Shirasawa, N.; Nguyet, T. T.; Hikichi, S.; Moro-oka, Y. Akita, M. Organometallics 2001, 20, 3582. See also: Uehara, K.; Hikichi, S.; Akita, M. Organometallics 2001, 20, 5002.
26. Akita, M.; Shirasawa, N.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1998, 973. Shirasawa, N.; Akita, M.; Hikichi, S.; Moro-oka, Y. J. Chem. Soc., Chem. Commun. 1999, 417. Shirasawa, N.; Nguyet, T. T.; Hikichi, S.; Moro-oka, Y. Akita, M. Organometallics 2001, 20, 3582. See also: Uehara, K.; Hikichi, S.; Akita, M. Organometallics 2001, 20, 5002.
27. Kisko, J. L.; Hascall, T.; Parkin, G. J. Am. Chem. Soc. 1988, 110, 10561. Jewson, J. D.; Liable-Sands, L. M.; Yap, G. P. A.; Rheingold, A. L.; Theopold, K. H. Organometallics 1999, 18, 300. Schebler, P. J.; Mandimutsira, B. S.; Riordan, C. G.; Liable-Sands, L. M.; Incarvito, C. D.; Rheingold, A. L. J. Am. Chem. Soc. 2001, 123, 331.
28. Kisko, J. L.; Hascall, T.; Parkin, G. J. Am. Chem. Soc. 1988, 110, 10561. Jewson, J. D.; Liable-Sands, L. M.; Yap, G. P. A.; Rheingold, A. L.; Theopold, K. H. Organometallics 1999, 18, 300. Schebler, P. J.; Mandimutsira, B. S.; Riordan, C. G.; Liable-Sands, L. M.; Incarvito, C. D.; Rheingold, A. L. J. Am. Chem. Soc. 2001, 123, 331.
29. Kisko, J. L.; Hascall, T.; Parkin, G. J. Am. Chem. Soc. 1988, 110, 10561. Jewson, J. D.; Liable-Sands, L. M.; Yap, G. P. A.; Rheingold, A. L.; Theopold, K. H. Organometallics 1999, 18, 300. Schebler, P. J.; Mandimutsira, B. S.; Riordan, C. G.; Liable-Sands, L. M.; Incarvito, C. D.; Rheingold, A. L. J. Am. Chem. Soc. 2001, 123, 331.
30. Trofimenko, S. J. Am. Chem. Soc. 1966, 88, 1842. Trofimenko, S. Inorg. Synth. 1970, 12, 99. Trofimenko, S. Chem. Rev. 1993, 93, 943. Trofimenko, S. Scorpionates-The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, 1999.
31. Trofimenko, S. J. Am. Chem. Soc. 1966, 88, 1842. Trofimenko, S. Inorg. Synth. 1970, 12, 99. Trofimenko, S. Chem. Rev. 1993, 93, 943. Trofimenko, S. Scorpionates-The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, 1999.
32. Trofimenko, S. J. Am. Chem. Soc. 1966, 88, 1842. Trofimenko, S. Inorg. Synth. 1970, 12, 99. Trofimenko, S. Chem. Rev. 1993, 93, 943. Trofimenko, S. Scorpionates-The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, 1999.
33. Trofimenko, S. J. Am. Chem. Soc. 1966, 88, 1842. Trofimenko, S. Inorg. Synth. 1970, 12, 99. Trofimenko, S. Chem. Rev. 1993, 93, 943. Trofimenko, S. Scorpionates-The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, 1999.
34. R. 4-pz-H, the hydrogen atom at the 4-position of the pyrazolyl ring. Compound numbers with ′ (prime) are for nickel derivatives.
35. Copper complexes can be raised as typical examples. Abel, E. W.; Stone, F. G. A.; Wilkinson, G. Comprehensive Organometallic Chemistry II; Pergamon: Oxford, 1995; Vol. 3.
36. Sonogashira, K.: Tohda, Y.; Hagihara, N. Tetrahedron Lett. 1975, 50, 4467. Bruce, M. I.; Humphery, M. G.; Matisons, J. G.; Roy, S. K.; Swincer, A. G. Aust. J. Chem. 1984, 37, 1955.
37. Sonogashira, K.: Tohda, Y.; Hagihara, N. Tetrahedron Lett. 1975, 50, 4467. Bruce, M. I.; Humphery, M. G.; Matisons, J. G.; Roy, S. K.; Swincer, A. G. Aust. J. Chem. 1984, 37, 1955.
38. Akita, M.; Hikichi, S. Bull. Chem. Soc. Jpn. 2002, 75, in press. Hikichi, S.; Yoshizawa, M.; Sasakura, Y.; Komatsuzaki, H.; Moro-oka, Y.; Akita, M. Chem.-A Eur. J. 2001, 7, 5011. See also references sited in these papers.
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40. For related dioxygen complexes with Tp and tripodal ligands, see: Reinaud, O. M.; Theopold, K. H. J. Am. Chem. Soc. 1994, 116, 6979. Reinaud, O. M.; Yap, G. P. A.; Rheingold, A. L.; Theopold, K. H. Angew. Chem., Int. Ed. Engl. 1995, 34, 2051. Theopold, K. H.; Reinaud, O. M.; Doren, D.; Konecny, R. In Third World Congress on Oxidation Catalysis; Grasselli, R. K., Oyama, S. T., Gaffney, A. M., Lyons, J. E., Eds.; Elsevier: Amsterdam, 1997; pp 1081-1088. Thyagarajan, S.; Incarvito, C. D.; Rheingold, A. L.; Theopold, K. H. Chem. Commun. 2001, 2198. Mandimutsira, B. S.; Yamarik, J. L.; Brunold, T. C.; Gu, W.; Cramer, S. P.; Riordan, C. G. J. Am. Chem. Soc. 2001, 123, 9194. Hu, Z.; George, G. N.; Gorun, S. M. Inorg. Chem. 2001, 40, 4812. Hu, Z.; Williams, R. D.; Tran, D.; Spiro, T. G.; Gorun, S. M. J. Am. Chem. Soc. 2000, 122, 3556. Diaconu, D.; Hu, Z.; Gorun, S. M. J. Am. Chem. Soc. 2002, 124, 1564
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