Thermally stable coordinatively unsaturated alkyl complexes resistant to β-hydride elimination: Tp(iPr)M-CH2CH3 (M = Co,Fe)

Chemical Communications

Volumn , Issue 5, 1999, Pages 417-418

  Shirasawa, Nobuhiko ^a   Akita, Munetaka ^a   Hikichi, Shiro ^a   Moro Oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; COBALT COMPLEX; HYDROTRIS(3,5 DIISOPROPYLPYRAZOLYL)BORATE DERIVATIVE; IRON COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; THERMOSTABILITY;

EID: 0033531422     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a809441a     Document Type: Article

References (9)

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7. Several examples of coordinatively unsaturated hydrocarbyl complexes kinetically stabilized by bulky ligands are known. See, for example: B. K. Bower and H. G. Tennent, J. Am. Chem. Soc., 1972, 94, 2512; A. Kose, E. Solari, C. Floriani, A. Chiesi-Villa, C. Rizzoli and N. Re, J. Am. Chem. Soc., 1994, 116, 9123; R. C. Kerber, Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1995, vol. 7, ch. 2.3.1.
8. Several examples of coordinatively unsaturated hydrocarbyl complexes kinetically stabilized by bulky ligands are known. See, for example: B. K. Bower and H. G. Tennent, J. Am. Chem. Soc., 1972, 94, 2512; A. Kose, E. Solari, C. Floriani, A. Chiesi-Villa, C. Rizzoli and N. Re, J. Am. Chem. Soc., 1994, 116, 9123; R. C. Kerber, Comprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1995, vol. 7, ch. 2.3.1.
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