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The structure of 1 will be reported elsewhere
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The structure of 1 will be reported elsewhere.
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note
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The crystallography of (2)·2MeOH revealed the exsistence of two independent molecules. The bond dinstances of Ni-O molecule (2.053 and 2.088 Å) in the other molecule in the cell also indicated the hydrogen bond between the methanol and metal bound hydroxo group; See supplementary material.
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30
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0344425228
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note
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The amount of p-nitrophenolate ion estimated from the absorption at 400 nm was not changed by the addition of a buffer solution (CHES pH 8.2). Therefore, neutral p-nitrophenol was not generated in this reaction system.
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31
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0345719915
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note
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A plot of k(p-NPA) vs. the added ethanol concentration gave a straight line. The result indicates a 1 : 1 adduct of alcohol and monomeric (hydroxo)nickel(II) complex is the reasonable nucleophile toward the substrate.
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0015497798
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