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Volumn 107, Issue 39, 2003, Pages 10894-10905

Reduction of polyfluorinated compounds

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CYCLIC VOLTAMMETRY; DIFFUSION IN SOLIDS; DISSOCIATION; ELECTROCHEMISTRY; ELECTRON TRANSPORT PROPERTIES; RATE CONSTANTS; REDUCTION; SUBSTRATES; THERMODYNAMIC PROPERTIES; VOLUME FRACTION;

EID: 0142091722     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp034846b     Document Type: Article
Times cited : (25)

References (133)
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    • 35449001112 scopus 로고    scopus 로고
    • Tidwell, T. T., Ed.; Academic Press: New York
    • (d) Savéant, J.-M. In Advances in Physical Organic Chemistry; Tidwell, T. T., Ed.; Academic Press: New York, 2000; Vol. 35, pp 117-192.
    • (2000) Advances in Physical Organic Chemistry , vol.35 , pp. 117-192
    • Savéant, J.-M.1
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    • 85087247013 scopus 로고    scopus 로고
    • note
    • i is its diffusion coefficient.
  • 76
    • 0000473250 scopus 로고    scopus 로고
    • Brandrup, J,l Immergut, E., Grulke, E. A., Eds.; Wiley: New York; Chapter VII
    • (d) Grulke, E. A. In Polymers Handbook, 4th ed.; Brandrup, J,l Immergut, E., Grulke, E. A., Eds.; Wiley: New York, 1999; Chapter VII, pp 675-714.
    • (1999) Polymers Handbook, 4th Ed. , pp. 675-714
    • Grulke, E.A.1
  • 83
    • 85087245765 scopus 로고    scopus 로고
    • note
    • 2e = [S]/[M] is the excess factor generally used for a mediated transfer of two electrons. They could also be obtained from digital simulation using Digisim (BioAnalytical System).
  • 97
    • 85087244445 scopus 로고    scopus 로고
    • note
    • a values of phenoxide ions.
  • 99
    • 0142137430 scopus 로고    scopus 로고
    • note
    • Ar-Cl = 0.07 V for aryl groups expanding similar charge delocalization (observed for Ar = naphthyl and 4-acetylphenyl).
  • 100
    • 85087246878 scopus 로고    scopus 로고
    • note
    • -1.
  • 102
    • 0142105677 scopus 로고    scopus 로고
    • note
    • The value of α = 0.43 could be related to the asymmetric nature of the ET reaction but could also be explained as the influence of the high value of the uncompensated resistance in THF solution.
  • 114
    • 0142137428 scopus 로고
    • Perfluoroalkyl radical studies
    • Dissertation Thesis for University of Souther California
    • (b) Fernandez, R. E. Perfluoroalkyl radical studies, Dissertation Thesis for University of Souther California, 1987; p 15.
    • (1987) , pp. 15
    • Fernandez, R.E.1
  • 125
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    • note
    • 61c
  • 131
    • 0142042169 scopus 로고    scopus 로고
    • note
    • An apparent coefficient transfer of 0.4 could be deduced from the reduction of the F-2,4-dimethyl-3-ethyl-3-pentyl radical in ref 56b.
  • 132
    • 85087246031 scopus 로고    scopus 로고
    • note
    • p.
  • 133
    • 85087245125 scopus 로고    scopus 로고
    • note
    • 20


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.