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2e = [S]/[M] is the excess factor generally used for a mediated transfer of two electrons. They could also be obtained from digital simulation using Digisim (BioAnalytical System).
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85087244445
-
-
note
-
a values of phenoxide ions.
-
-
-
-
99
-
-
0142137430
-
-
note
-
Ar-Cl = 0.07 V for aryl groups expanding similar charge delocalization (observed for Ar = naphthyl and 4-acetylphenyl).
-
-
-
-
100
-
-
85087246878
-
-
note
-
-1.
-
-
-
-
102
-
-
0142105677
-
-
note
-
The value of α = 0.43 could be related to the asymmetric nature of the ET reaction but could also be explained as the influence of the high value of the uncompensated resistance in THF solution.
-
-
-
-
103
-
-
0032504424
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note
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An apparent coefficient transfer of 0.4 could be deduced from the reduction of the F-2,4-dimethyl-3-ethyl-3-pentyl radical in ref 56b.
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