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Volumn 119, Issue 40, 1997, Pages 9527-9540

Dynamics of bond breaking in ion radicals. Mechanisms and reactivity in the reductive cleavage of carbon-fluorine bonds of fluoromethylarenes

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOFLUORINE DERIVATIVE;

EID: 0030774162     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971094o     Document Type: Article
Times cited : (89)

References (46)
  • 1
    • 9844251084 scopus 로고    scopus 로고
    • Université Denis Diderot
    • (a) Université Denis Diderot,
  • 2
    • 9844264705 scopus 로고    scopus 로고
    • ESPCI
    • (b) ESPCI.
  • 6
    • 0002522621 scopus 로고
    • Electrochemical Carbonization of Fluoropolymers
    • Thrower, Ed.; Marcel Dekker: New York
    • (a) Kavan, L. Electrochemical Carbonization of Fluoropolymers. In Chemistry and Physics of Carbon; Thrower, Ed.; Marcel Dekker: New York, 1991; pp 70-163.
    • (1991) Chemistry and Physics of Carbon , pp. 70-163
    • Kavan, L.1
  • 16
    • 0001887557 scopus 로고
    • Dissociative Electron Transfer
    • Mariano, P. S., Ed.; JAI Press: New York
    • Savéant, J. M. Dissociative Electron Transfer. In Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: New York, 1994; Vol. IV, pp 53-116.
    • (1994) Advances in Electron Transfer Chemistry , vol.4 , pp. 53-116
    • Savéant, J.M.1
  • 22
    • 0000821227 scopus 로고
    • Electrochemical Reactions
    • Bernasconi, C. F., Ed.; Wiley: New York, 4/E
    • (a) Andrieux, C. P.; Savéant, J.-M. Electrochemical Reactions. In Investigations of rates and Mechanisms of Reactions; Bernasconi, C. F., Ed.; Wiley: New York, 1986; Vol. 6, 4/E, Part 2, pp 305-390.
    • (1986) Investigations of Rates and Mechanisms of Reactions , vol.6 , Issue.PART 2 , pp. 305-390
    • Andrieux, C.P.1    Savéant, J.-M.2
  • 27
    • 9844237415 scopus 로고    scopus 로고
    • note
    • 10a,11b for mediators giving rise to a small catalytic effect
  • 36
    • 33845279095 scopus 로고    scopus 로고
    • See Table 2 in ref 9a and the references quoted therein
    • 0 = -1.50 meV. Marcus, Y. Pure Appl Chem. 1985, 57, 1103. Marcus, Y.; Kamlet, M. J.; Taft, R. W. J. Phys. Chem. 1988, 92, 3613.
  • 37
    • 33845279095 scopus 로고    scopus 로고
    • note
    • 0 = -1.50 meV. Marcus, Y. Pure Appl Chem. 1985, 57, 1103. Marcus, Y.; Kamlet, M. J.; Taft, R. W. J. Phys. Chem. 1988, 92, 3613.
  • 38
    • 0007901475 scopus 로고
    • 0 = -1.50 meV. Marcus, Y. Pure Appl Chem. 1985, 57, 1103. Marcus, Y.; Kamlet, M. J.; Taft, R. W. J. Phys. Chem. 1988, 92, 3613.
    • (1985) Pure Appl Chem. , vol.57 , pp. 1103
    • Marcus, Y.1
  • 40
    • 9844269971 scopus 로고    scopus 로고
    • note
    • Eq 6, being based on a Born model of solvation, is likely to be a rather poor representation of the differences between a H-bonding solvent and an aprotic solvent although the predictions deriving from the size of the charge location volume and to the center-to center distant are most likely correct.


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