Stable and controlled amphoteric doping by encapsulation of organic molecules inside carbon nanotubes

Nature Materials

Volumn 2, Issue 10, 2003, Pages 683-688

  Takenobu, Taishi ^a,b   Takano, Takumi ^a   Shiraishi, Masashi ^c   Murakami, Yousuke ^c   Ata, Masafumi ^c   Kataura, Hiromichi ^d   Achiba, Yohji ^d   Iwasa, Yoshihiro ^a,b  

^a TOHOKU UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c SONY CORPORATION   (Japan)

^d TOKYO METROPOLITAN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARRIER MOBILITY; CHARGE TRANSFER; ELECTRONIC PROPERTIES; IONIZATION; SEMICONDUCTING ORGANIC COMPOUNDS; SEMICONDUCTOR DOPING; X RAY DIFFRACTION ANALYSIS;

AMPHOTERIC DOPING; MOLECULAR ELECTRONICS; ORGANIC MOLECULES;

CARBON NANOTUBES;

BIOMATERIAL; CARBON NANOTUBE; ORGANIC COMPOUND;

ARTICLE; CHEMISTRY; CONFORMATION; CRYSTALLIZATION; CRYSTALLOGRAPHY; EQUIPMENT DESIGN; EVALUATION; INSTRUMENTATION; MACROMOLECULE; MATERIALS TESTING; METHODOLOGY; NANOTECHNOLOGY; PH; SEMICONDUCTOR; SYNTHESIS;

COATED MATERIALS, BIOCOMPATIBLE; CRYSTALLIZATION; CRYSTALLOGRAPHY; EQUIPMENT DESIGN; HYDROGEN-ION CONCENTRATION; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; MOLECULAR CONFORMATION; NANOTECHNOLOGY; NANOTUBES, CARBON; ORGANIC CHEMICALS; SEMICONDUCTORS;

EID: 0142090810     PISSN: 14761122     EISSN: None     Source Type: Journal    
DOI: 10.1038/nmat976     Document Type: Article

References (29)

1. Dresselhaus, M. S., Dresselhaus, G & Avouris, P. (eds.) Carbon Nanotubes (Spring, Berlin, 2001).
2. Franklin, N. R. et al. Integration of suspended carbon nanotube arrays into electronic devices and electromechanical systems. Appl. Phys. Lett. 81, 913-915 (2002).
3. Fuhrer, M. S., Kim, B. M., Dürkop, T. & Brintlinger, T. High-mobility nanotube transistor memory. Nano Lett. 2, 755-759 (2002).
4. Liang, W. et al. Fabry-Perot interference in a nanotube electron waveguide. Nature 411, 665-669 (2001).
5. Kong, J. et al. Quantum interference and ballistic transmission in nanotube electron wave-guides. Phys. Rev. Lett. 87, 106801 (2001).
6. Javey, A. et al. High-κ dielectrics for advanced carbonnanotube transistors and logic gates. Nature Mater. 1, 241-246 (2002).
7. Heinze, S. et al. Carbon nanotubes as schottky barrier transistors. Phys. Rev. Lett. 89, 106801 (2002).
8. Derycke, V., Martel, R., Appenzeller, J. & Avouris, P. Controlling doping and carrier injection in carbon nanotube transistors. Appl. Phys. Lett. 80, 2773-2774 (2002).
9. Kong, J. et al. Nanotube molecular wires as chemical sensors. Science 287, 622-625 (2000).
10. Collins, P., Bradley, K., Ishiigami, M. & Zettl, A. Extreme oxygen sensitivity of electronic properties of carbon nanotubes. Science 287, 1801-1804 (2000).
11. Martel, R. et al. Ambipolar electrical transport in semiconducting single-wall carbon nanotubes. Phys. Rev. Lett. 87, 106801 (2001).
12. Zhou, C., Kong, J., Yenilmez, E. & Dai, H. Modulated chemical doping of individual carbon nanotubes. Science 290, 1552-1555 (2000).
13. Kazaoui, S., Minami, N., Jacquemin, R., Kataura, H. & Achiba, Y. Amphoteric doping of single-wall carbon-nanotube thin films as probed by optical absorption spectroscopy. Phys. Rev. B 60, 13339-13342 (1999).
14. Kazaoui, S., Minami, N., Matsuda, N., Kataura, H. & Achiba, Y. Electrochemical tuning of electronic states in single-wall carbon nanotubes studied by in situ absorption spectroscopy and ac resistance. Appl. Phys. Lett. 78, 3433-3435 (2001).
15. Jouguelet, E., Mathis, C. & Petit, P. Controlling the electronic properties of single-wall carbon nanotubes by chemical doping. Chem. Phys. Lett. 318, 561-564 (2000).
16. Kong, J. & Dai, H. Full and modulated chemical gating of individual carbon nanotubes by organic amine. J. Phys. Chem. B 105, 2890-2893 (2001).
17. Shim, M., Javey, A., Kam, N. W. S. & Dai, H. Polymer functionalization for air-stable n-type carbon nanotube field-effect transistors. J. Am. Chem. Soc. 123, 11512-11513 (2001).
18. Lee, J. et al. Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes. Nature 415, 1005-1008 (2002).
19. Hornbaker, D. J. et al. Mapping the one-dimensional peapod structures. Science 295, 828-831 (2002).
20. Kataura, H. et al. Optical properties of fullerene and non-fullerene peapods. Appl. Phys. A 74, 1-6 (2002).
21. Shiraishi, M., Takenobu, T., Yamada, A., Ata, M. & Kataura, H. Hydrogen storage in single-walled carbon nanotube bundles and peapods. Chem. Phys. Lett. 358, 213-218 (2002).
22. Maniwa, Y. et al. Anomaly of x-ray diffraction profile in single-walled carbon nanotubes. Jpn J. Appl. Phys. 38, L668-L670 (1999).
23. Seki, N. Ionization energies of free molecules and molecular solids. Mol. Cryst. Liq. Cryst. 171, 255-270 (1989).
24. 60 in carbon nanotubes. Nature 396, 323-323 (1998).
25. Morgan, D. A., Sloan, J. & Green, M. L. H. Direct imaging of o-carborane molecules with single walled carbon nanotubes. Chem. Comm. 20, 2442-2443 (2002).
26. Rao, A. M., Eklund, P. C., Bandow, S., Thess, A. & Smalley, R. E. Evidence for charge transfer in doped carbon nanotube bundles from Raman scattering. Nature 388, 257-259 (1997).
27. Iwasa, Y. et al. Intercalation processes of single-walled carbon nanotube ropes. New Diam. Front. C. Tec. 12, 325-330 (2002).
28. Kataura, H. et al. Optical properties of single-wall carbon nanotubes. Synth. Met. 103, 2555-2558 (1999).
29. Matsuzaki, S., Kawata, R. & Toyoda, K. Raman spectra of conducting TCNQ salt; estimation of the degree of charge transfer from vibrational frequencies. Solid State Commun. 33, 403-405 (1980).