A novel procedure for conversion of epoxides to α -hydroxyphosphonates with a trialkylphosphite mediated by LiClO4

Tetrahedron Letters

Volumn 44, Issue 43, 2003, Pages 7933-7935

  Azizi, Najmoddin ^a   Saidi, Mohammad R ^a  

^a SHARIF UNIVERSITY OF TECHNOLOGY   (Iran)

Author keywords

Epoxide; Lithium perchlorate; Trialkylphosphite; hydroxyphosphonates

Indexed keywords

EPOXIDE; LITHIUM PERCHLORATE; PERCHLORATE; PHOSPHITE; PHOSPHONIC ACID DERIVATIVE; TRIALKYLPHOSPHITE; UNCLASSIFIED DRUG;

ANALYTIC METHOD; ARTICLE; CHEMICAL MODIFICATION; CHEMICAL PROCEDURES; CHEMICAL REACTION; STEREOCHEMISTRY;

EID: 0141596919     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.09.002     Document Type: Article

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28. 4, and the solvent was removed. Almost pure product was obtained, further purification was carried out by column chromatography on basic alumina eluting with ethyl acetate/hexane, if needed. All compounds were characterized on the basis of spectroscopic data (IR, NMR, MS) and by comparison with those reported in the literature.
29. cp=161.2 Hz).