Helical, chiral polyisocyanides bearing ferrocenyl groups as pendants: Synthesis and properties

Angewandte Chemie - International Edition

Volumn 42, Issue 36, 2003, Pages 4349-4352

  Hida, Noriyuki ^a   Takei, Fumie ^a   Onitsuka, Kiyotaka ^a   Shiga, Keiichiro ^b   Asaoka, Sadayuki ^b   Iyoda, Tomokazu ^b   Takahashi, Shigetoshi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Electrochemistry; Ferrocene; Helical structures; Polyisocyanides; Polymers

Indexed keywords

COMPLEXATION; CONFORMATIONS; ELECTROLYTIC ANALYSIS; OXIDATION; POLYMERIZATION; ULTRAVIOLET SPECTROSCOPY;

HELICES;

CYANIDES;

CYANIDE; FERROCENE DERIVATIVE; FERROCENYLISOCYANIDE DERIVATIVE; PALLADIUM COMPLEX; PLATINUM COMPLEX; POLYMER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; CONFORMATIONAL TRANSITION; OPTICAL ROTATION; OXIDATION; POLYMERIZATION; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY;

EID: 0141534414     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351456     Document Type: Article

References (30)

1. S. Kobayashi, Catalysis in Precision Polymerization, Wiley, Chichester, 1997.
2. P. Nguyen, P. Gomez-Elipe, I. Manners, Chem. Rev. 1999, 99, 1515.
3. For recent papers, see: a) S. Nlate, J. Ruiz, V. Sartor, R. Navarro, J. Blaiz, D. Astruc, Chem. Eur. J. 2000, 6, 2544;
4. b) R. Resendes, J. A. Massey, K. Temple, L. Cao, K. N. Power-Billard, M. A. Winnik, I. Manners, Chem. Eur. J. 2001, 7, 2414.
5. For reviews, see: a) T. Nakano, Y. Okamoto, Chem. Rev. 2001, 101, 4013;
6. b) J. J. L. M. Cornelissen. A. E. Rowan, R. J. M. Nolte, N. A. J. M. Sommerdijk, Chem. Rev. 2001, 101, 4039.
7. a) K. Onitsuka, T. Joh, S. Takahashi, Bull. Chem. Soc. Jpn. 1992, 65, 1179;
8. b) K. Onitsuka, K. Yanai, F. Takei, T. Joh, S. Takahashi, Organometallics 1994, 13, 3862.
9. a) F. Takei, K. Yanai, K. Onitsuka, S. Takahashi, Angew. Chem. 1996, 108, 1634; Angew. Chem. Int. Ed. Engl. 1996, 35, 1554; b) F. Takei, K. Yanai, K. Onitsuka, S. Takahashi, Chem. Eur. J. 2000, 6, 983.
10. a) F. Takei, K. Yanai, K. Onitsuka, S. Takahashi, Angew. Chem. 1996, 108, 1634; Angew. Chem. Int. Ed. Engl. 1996, 35, 1554; b) F. Takei, K. Yanai, K. Onitsuka, S. Takahashi, Chem. Eur. J. 2000, 6, 983.
11. b) F. Takei, K. Yanai, K. Onitsuka, S. Takahashi, Chem. Eur. J. 2000, 6, 983.
12. a) M. Muller, R. Zentel, Macromolecules 1996, 29, 1609;
13. b) S. Mayer, G. Maxein, R. Zentel, Macromolecules 1998, 31, 8522;
14. c) K. Maeda, Y. Okamoto, Macromolecules 1999, 32, 974.
15. a) A. Ueno, K. Takahashi, J. Anzai, T. Osa, J. Am. Chem. Soc. 1981, 103, 6410;
16. b) O. Pieroni, A. Fissi, N. Angelini, F. Lenci, Acc. Chem. Res. 2001, 34, 9.
17. a) L. Angiolini, D. Caretti, L. Giorgini, E. Salatelli, A. Altomare, C. Carlini, R. Solaro, Polymer 1998, 39, 6621;
18. b) L. Angiolini, R. Bozio, L. Giorgini, D. Pedron, G. Turco, A. Dauru, Chem. Eur. J. 2002, 8, 4241.
19. M. Fujiki, J. Am. Chem. Soc. 2000, 122, 3336.
20. a) E. Yashima, K. Maeda, Y. Okamoto, Nature 1999, 399, 449;
21. b) K. Maeda, E. Yashima, Yuki Gosei Kagaku Kyokaishi 2002, 60, 878.
22. For the synthesis of chiral ferrocenyl alcohol, see: a) J. Wright, L. Frambes, P. Reeves, J. Organomet. Chem. 1994, 476, 215;
23. L. Schwink, P. Knochel, Tetrahedron Lett. 1996, 37, 25.
24. 3).
25. F. Takei, H. Hayashi, K. Onitsuka, N. Kobayashi, S. Takahashi, Angew. Chem. 2001, 113, 4216; Angew. Chem. Int. Ed. 2001, 40, 4092.
26. F. Takei, H. Hayashi, K. Onitsuka, N. Kobayashi, S. Takahashi, Angew. Chem. 2001, 113, 4216; Angew. Chem. Int. Ed. 2001, 40, 4092.
27. I. Cuadrado, C. M. Casado, B. Alonso, M. Moran, J. Losada, V. Belsky, J. Am. Chem. Soc. 1997, 119, 7613;
28. K.-W. Poon, Y. Yan, X.-Y. Li, D. K. P. Ng, Organometallics 1999, 18, 3528.
29. 6] under potentiostatic conditions at 1.0 V (oxidation) and 0.2 V (reduction) versus Ag/AgCl. A platinum mesh was used as a working electrode. A platinum wire and an Ag/AgCl electrode were used as a counter electrode and a reference electrode, respectively.
30. F. G. Herring, R. A. N. McLean, Inorg. Chem. 1972, 11, 1667.