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0141611594
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note
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(b) Reaction step A follows the procedure in the above reference. For step B, typically the substrate is immersed in a mixed solution of 500 μL of sodium tetraborate aqueous buffer (0.1 M, pH 8.5) and 400 μL of dimethylforamide with 1 mg of 2. The concentration of the aqueous solution of carbonaceous materials 3 in step C could be varied over a wide range without affecting the surface immobilization process. The reaction in step B typically takes 12 h, and the surface assembly in step C is finished within 2 h for both SWNHs and SWNTs.
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0141723229
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note
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The optical characterization of the surface functionalization process is currently underway and will be reported in due course.
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33
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0141611595
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note
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(a) Oxygen treatment is critical for opening nanosized windows on SWNHs and for such applications as gas adsorption.
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34
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2 treatment from the thermogravimetric - mass spectrum analysis.
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35
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0141834594
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note
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Typical experimental conditions for dispersing oxidized SWNHs are sonication for 1 h, centrifugation at 10 000 rpm for 5 min, and filtration through a 0.45-μm filter paper.
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36
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0141499781
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note
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SWNHs could barely be observed in the hydroxyl area of the substrate (ref Figure S2B).
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37
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0141499784
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note
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A pipet was used to transfer the solution of 1 along an open end of the microchannels of a poly(dimethylsiloxane) stamp, and the reaction was allowed to proceed for 20 min. The rest of the procedure is the same as that described previously.
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38
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0033543598
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Zhang, Y.; Ichihashi, T.; Landree, E.; Nihey, F.; Iijima, S. Science 1999, 285, 1719.
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39
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40
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0141611596
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note
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2O and cut into short strands with ultrasonication.
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41
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0141611593
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note
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Because of the presence of the SDS surfactant and the high aspect ratio of SWNTs, compared with that of SWNHs, the process of the surface immobilization of SWNTs is different, and the surface density of SWNTs is not as high as that of SWNHs. (The assembly of both SWNHs and SWNTs is finished within 2 h, and the surface density is not increased afterwards.)
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42
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18044400616
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