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Volumn 19, Issue 16, 2003, Pages 6443-6448

Molecular orientation distributions in protein films. V. Cytochrome c adsorbed to a sulfonate-terminated, self-assembled monolayer

Author keywords

[No Author keywords available]

Indexed keywords

PROTEIN FILMS;

EID: 0042570793     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la034167s     Document Type: Article
Times cited : (32)

References (36)
  • 20
    • 0034163275 scopus 로고    scopus 로고
    • Other combinations of polarized spectroscopic techniques can also be employed to determine the molecular orientation distribution in a thin film of chromophores. See: Simpson, G. J.; Westerbuhr, S. G.; Rowlen, K. L. Anal. Chem. 2000, 72, 887-898.
    • (2000) Anal. Chem. , vol.72 , pp. 887-898
    • Simpson, G.J.1    Westerbuhr, S.G.2    Rowlen, K.L.3
  • 28
    • 0003373776 scopus 로고
    • In Proteins at Interfaces II; Horbett, T. A., Brash, J. L., Eds.; American Chemical Society: Washington, DC
    • We note that the assumptions of the Langmuir model are not likely met in these experiments. Specifically, the inherent assumptions that only one type of surface site is present, that lateral interactions between adsorbed molecules are absent, and that the adsorption process is reversible and measured at equilibrium are probably not valid. Thus the measured binding constant is termed "apparent". See: (a) Brash, J. L.; Horbett, T. A. In Proteins at Interfaces II; Horbett, T. A., Brash, J. L., Eds.; ACS Symposium Series 602; American Chemical Society: Washington, DC, 1995; pp 1-23.
    • (1995) ACS Symposium Series , vol.602 , pp. 1-23
    • Brash, J.L.1    Horbett, T.A.2
  • 31
    • 0041604147 scopus 로고    scopus 로고
    • Note
    • Calculated by approximating the shape of hcyt c as a rectangular box with dimensions of 25 A × 25 A × 37 A (ref 8) and assuming that adsorption via all six faces of the box is equally probable.
  • 36
    • 0043106909 scopus 로고    scopus 로고
    • Note
    • The assumptions and problems inherent in using ATM roughness measurements to evaluate the influence of substrate surface roughness on molecular orientation measurements are discussed in detail in ref 26.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.