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Volumn 19, Issue 17, 2003, Pages 6590-6593

Two-dimensional aggregation of species with weak and strong bonding interactions: Modeling the growth of self-assembled alkylsiloxane monolayers

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Indexed keywords

HYDROXYLATED SUBSTRATES;

EID: 0042379880     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la030100t     Document Type: Article
Times cited : (24)

References (31)
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    • note
    • Note, initially, the adsorbed clusters must not necessarily be either completely ordered or ordered in the same way as the final monolayer. We neglect, however, the influence of any vertical reorganization on the growth of the monolayer.
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    • note
    • Note, for very low alkylsilane concentrations, that is, below 0.025 mM, an induction period has been observed in ref 15. Under these conditions, however, desorption might compete with adsorption throughout the monolayer growth. Simulations on the basis of our model including a desorption probability for mobile clusters indeed reproduce this characteristic feature at low alkylsilane concentrations.


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