Mesyloxy-group migration as the stereoselective preparation method of various functionalized olefins and its reaction mechanism

Organic Letters

Volumn 3, Issue 5, 2001, Pages 743-746

  Yamazaki, Takashi ^a   Hiraoka, Shuichi ^a   Sakamoto, Johei ^a   Kitazume, Tomoya ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

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ARTICLE;

EID: 0042262416     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol007060u     Document Type: Article

References (45)

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44. 2). After usual workup, the crude material was dissolved in MeOH where 4.0 equiv of NaOMe was added at 0 °C. Stirring at room temperature (0.5 h) and the usual workup and purification by silica gel column chromatography gave 21 (0.062 g, 0.352 mmol) in 95% yield.
45. 2.