Vinylic C-F bond activation with low-valent zirconocene: The generation and cross-coupling reactions of 1-fluorovinylzirconocene

Tetrahedron Letters

Volumn 40, Issue 40, 1999, Pages 7261-7265

  Fujiwara, Masaki ^a,b   Ichikawa, Junji ^a,b   Okauchi, Tatsuo ^a   Minami, Toru ^a  

^a KYUSHU INSTITUTE OF TECHNOLOGY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

Coupling reactions; Fluorine; Fluorine compounds; Olefins; Zirconium; Zirconium compounds

Indexed keywords

ALKENE; DIMETHYLAMINE; FLUORINE; IODIDE; ORGANOFLUORINE DERIVATIVE; PALLADIUM; TRIFLUOROETHANOL; VINYL DERIVATIVE; ZIRCONIUM; ZIRCONIUM DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0033215508     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)01491-4     Document Type: Article

References (32)

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30. This zirconacyclopropanation/β-elimination protocol did not work on oxygen-free substrates such as 1,1-difluoroethylene, 2,2-difluorovinyldimethylphenylsilane, and tributyl(2,2-difluorovinyl)tin, presumably due to the difficulty in coordination of these olefins to the zirconocene complex.
31. FH=20-23 Hz), which were in accordance with that of 5fe (20 Hz).
32. +); found 271.1356.