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Even though the system has a perfect threefold symmetry, the transmission is not exactly divided by two, since part of the electron wave function is reflected on the conductor, in particular on the heptagons. The presence of the heptagons is also responsible for the appearance of a small asymmetry in the conductance, compared to a pristine nanotube.
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Rectifying behavior will be induced by asymmetric transmission curves, provided that an asymmetric potential profile breaks the geometrical symmetry of the device. For a detailed discussion of the effect of the potential drop see: W. Tian, S. Datta, S. Hong, R. Reifenberger, J. I. Henderson, and C. P. Kubiak, 1. Chem. Phys. 109, 2874 (1998).
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