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84985531954
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Bimetallic complexes have been prepared by reaction of zirconocene-stabilized benzyne complexes with transition and main-group metal compounds: (a) Erker, G.; Dorf, U.; Mynott, R.; Tsay, Y.-H.; Krüger, C. Angew. Chem., Int. Ed. Engl. 1985, 24, 584. (b) Albrecht, M.; Erker, G.; Krüger, C. SynLett 1993, 441. (c) de Rege, F. M. G.; Davis, W. M.; Buchwald, S. L. Organometallics 1995, 14, 4799.
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Krüger, C.5
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15
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84985723249
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Bimetallic complexes have been prepared by reaction of zirconocene- stabilized benzyne complexes with transition and main-group metal compounds: (a) Erker, G.; Dorf, U.; Mynott, R.; Tsay, Y.-H.; Krüger, C. Angew. Chem., Int. Ed. Engl. 1985, 24, 584. (b) Albrecht, M.; Erker, G.; Krüger, C. SynLett 1993, 441. (c) de Rege, F. M. G.; Davis, W. M.; Buchwald, S. L. Organometallics 1995, 14, 4799.
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Krüger, C.3
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16
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0001332812
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Bimetallic complexes have been prepared by reaction of zirconocene- stabilized benzyne complexes with transition and main-group metal compounds: (a) Erker, G.; Dorf, U.; Mynott, R.; Tsay, Y.-H.; Krüger, C. Angew. Chem., Int. Ed. Engl. 1985, 24, 584. (b) Albrecht, M.; Erker, G.; Krüger, C. SynLett 1993, 441. (c) de Rege, F. M. G.; Davis, W. M.; Buchwald, S. L. Organometallics 1995, 14, 4799.
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Diederich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, Germany, Chapter I
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(a) Negishi, E.-I.; Liu, F. In Metal-catalyzed Cross-coupling Reactions; Diederich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, Germany, 1998; Chapter I.
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Metal-catalyzed Cross-coupling Reactions
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Negishi, E.-I.1
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0344171459
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note
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1H NMR spectra.
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21
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0001029926
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Kranenburg, M.; van der Burgt, Y. E. M.; Kamer, P. C. J.; van Leeuwen, P. W. N.; Goubitz, K.; Fraanje, J. Organometallics 1995, 14, 3081.
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Van Leeuwen, P.W.N.4
Goubitz, K.5
Fraanje, J.6
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22
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0345465155
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note
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See Supporting Information for experimental details.
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23
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0345465154
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note
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Functional groups which can react with zirconocene-stabilized benzyne complexes without the agency of Pd, such as ketones, nitriles, carboxylic esters, carboxylic amides, and nitro groups, are incompatible with the reaction conditions.
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24
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0025936259
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Barr, K. J.; Watson, B. T.; Buchwald, S. L. Tetrahedron Lett. 1991, 32, 5465.
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Buchwald, S.L.3
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(a) Buchwald, S. L.; Lum, R. T.; Fisher, R. A.; Davis, W. M. J. Am. Chem. Soc. 1989, 111, 9113.
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Davis, W.M.4
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0345465152
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note
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