Synthesis and characterization of anionic and cationic poly(ferrocenylsilane) polyelectrolytes

Macromolecules

Volumn 36, Issue 17, 2003, Pages 6683-6688

  Hempenius, Mark A ^a   Brito, Fabiane F ^a   Vancso, G Julius ^a  

^a UNIVERSITY OF TWENTE   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

PH INDEPENDENT CHARGE DENSITY; POLYCATION SOLUTIONS; POLYFERROCENYLSILANE;

CHARACTERIZATION; CURRENT DENSITY; MACROMOLECULES; NEGATIVE IONS; ORGANOMETALLICS; PH EFFECTS; POLYSILANES; POSITIVE IONS; SYNTHESIS (CHEMICAL);

POLYELECTROLYTES;

EID: 0041319036     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma034432g     Document Type: Article

References (36)

1. For a recent review on poly(ferrocenylsilanes) see: Kulbaba, K.; Manners, I. Macromol. Rapid Commun. 2001, 22, 711.
2. Ni, Y.; Rulkens, R.; Manners, I. J. Am. Chem. Soc. 1996, 118, 4102.
3. Lammertink, R. G. H.; Hempenius, M. A.; Chan, V. Z.-H.; Thomas, E. L.; Vancso, G. J. Chem. Mater. 2001, 13, 429.
4. Korczagin, I.; Golze, S.; Hempenius, M. A.; Vancso, G. J. Chem. Mater., in press.
5. Lammertink, R. G. H.; Hempenius, M. A.; Thomas, E. L.; Vancso, G. J. J. Polym. Sci., Part B: Polym. Phys. 1999, 37, 1009.
6. Lammertink, R. G. H.; Hempenius, M. A.; Van den Enk, J. E.; Chan, V. Z.-H.; Thomas, E. L.; Vancso, G. J. Adv. Mater. 2000, 12, 98.
7. Cheng, J. Y.; Ross, C. A.; Chan, V. Z.-H.; Thomas, E. L.; Lammertink, R. G. H.; Vancso, G. J. Adv. Mater. 2001, 13, 1174.
8. Neuse, E. W.; Khan, F. B. D. Macromolecules 1986, 19, 269.
9. Kelch, S.; Rehahn, M. Macromolecules 1999, 32, 5818.
10. Power-Billard, K. N.; Manners, I. Macromolecules 2000, 33, 26.
11. (a) Hempenius, M. A.; Robins, N. S.; Lammertink, R. G. H.; Vancso, G. J. Macromol. Rapid Commun. 2001, 22, 30.
12. (b) Hempenius, M. A.; Robins, N. S.; Lammertink, R. G. H.; Vancso, G. J. IUPAC MACRO July 2000 Proc., Warsaw 2000, 2, 900; ISBN 83-904741-7-4.
13. Decher, G. Science 1997, 277, 1232.
14. Bertrand, P.; Jonas, A.; Laschewsky, A.; Legras, R. Macromol. Rapid Commun. 2000, 21, 319.
15. Wu, A.; Yoo, D.; Lee, J.-K.; Rubner, M. F. J. Am. Chem. Soc. 1999, 121, 4883.
16. Ladam, G.; Gergely, C.; Senger, B; Decher, G.; Voegel, J.-C.; Schaaf, P.; Cuisinier, F. J. G. Biomacromolecules 2000, 1, 674.
17. Hempenius, M. A.; Vancso, G. J. Macromolecules 2002, 35, 2445.
18. Wang, Z.; Lough, A.; Manners, I. Macromolecules 2002, 35, 7669.
19. Hempenius, M. A.; Robins, N. S.; Péter, M.; Kooij, E. S.; Vancso, G. J. Langmuir 2002, 18, 7629.
20. Halfyard, J.; Galloro, J.; Ginzburg, M.; Wang, Z.; Coombs, N.; Manners, I.; Ozin, G. A. Chem. Commun. 2002, 1746.
21. Calvo, E. J.; Wolosiuk, A. J. Am. Chem. Soc. 2002, 124, 8490.
22. Molyneux, P. Water-Soluble Synthetic Polymers: Properties and Behavior; CRC Press Inc.: Bota Raton, FL, 1984; Vol. II.
23. Gómez-Elipe, P.; Macdonald, P. M.; Manners, I. Angew. Chem., Int. Ed. Engl. 1997, 36, 762.
24. Willy, W. E.; McKean, D. R.: Garcia, B. A. Bull. Chem. Soc. Jpn. 1976, 49, 1989.
25. Itsuno, S.; Koizumi, T.; Okumura, C.; Ito, K. Synthesis 1995, 150.
26. To demonstrate the efficiency of this amination reaction, 1-bromodecane (0.71 g, 3.2 mmol) was added to a solution of lithium 1,1,3,3-tetramethyldisilazane (0.90 g, 6.4 mmol) in THF (10 mL) and dry DMSO (2.5 mL) at 0 °C. The mixture was stirred in ice for 1 h and 20 °C for 3 h. Acidic hydrolysis followed by neutralizaion with aqueous NaOH produced 1-aminodecane with complete conversion.
27. Shiratori, S. S.; Rubner, M. F. Macromolecules 2000, 33, 4213.
28. Schlenoff, J. B.; Wang, L.-J. Macromolecules 1991, 24, 6653.
29. Barnick, J. W. F. K.; van der Baan, J. L.; Bickelhaupt, F. Synthesis 1979, 787.
30. The solubility of 5 in water decreases above pH 7, while 8 becomes less soluble at pH < 6.
31. Xie, M.; Widlanski, T. S. Tetrahedron Lett. 1996, 37, 4443.
32. Truce, W. E.; Vrencur, D. J. J. Org. Chem. 1970, 35, 1226.
33. sp/C, plotted against polymer concentration C increase strongly with decreasing polymer concentrations (ref 16).
34. Šegudović, N.; Sertićc, S.; Kovač-Filipović, M.; Jarm, V. J. Chromatogr. A 1995, 704, 149.
35. Hellmann, H.; Teichmann, K.; Lingens, F. Chem. Ber. 1958, 91, 2427.
36. Kita, Y.; Haruta, J.; Segawa, J.; Tamura, Y. Tetrahedron Lett. 1979, 20, 4311.