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0037860477
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note
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2] (py=pyridine) by using bpy instead of py. Synthetic details and full characterization data are provided in Supporting Information.
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31
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0038198220
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note
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A larger amount of charge of the CO-bound cluster relative to the CO-free cluster (here the 1:1 stoichiometry is expected) arises from physical adsorption of 1, which was not removed from the surface by rinsing with water. This situation is also encountered for the following CO-terminated multilayers.
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32
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0037860479
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note
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The kinetic aspect of the CO dissociation from the multilayers will be detailed in our future publication.
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33
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0037522881
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note
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-1. All these infrared spectroscopic features are similar to the triruthenium derivatives as well as their monolayers prepared on Au. Upon electrolysis, the intensity of the v(CO) band decreases significantly.
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34
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0037522870
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note
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s(COO)].
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35
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0037860480
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note
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The relative intensity ratio of the two peaks is examined rather than their absolute intensity, because desorption of Au from the Au substrate surface was apparent during the immersion process for deposition, which directly affects the intensity of the infrared band.
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36
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0038536883
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note
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1/2 by 0.05 V.
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37
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0003561662
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Wiley, New York
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