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Volumn 42, Issue 25, 2003, Pages 2912-2915

Electrochemically controlled layer-by-layer deposition of metal-cluster molecular multilayers on gold

Author keywords

Cluster compounds; Electron transport; Multilayers; Nanotechnology; Surface chemistry

Indexed keywords

ELECTRIC POTENTIAL; ELECTROCHEMICAL ELECTRODES; ELECTRON TRANSPORT PROPERTIES; SELF ASSEMBLY;

EID: 0038715135     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351334     Document Type: Article
Times cited : (100)

References (40)
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    • a) D. M. Kolb, Angew. Chem. 2001, 113, 1198; Angew. Chem. Int. Ed. 2001, 40, 1162;
    • (2001) Angew. Chem. , vol.113 , pp. 1198
    • Kolb, D.M.1
  • 9
    • 0035794922 scopus 로고    scopus 로고
    • a) D. M. Kolb, Angew. Chem. 2001, 113, 1198; Angew. Chem. Int. Ed. 2001, 40, 1162;
    • (2001) Angew. Chem. Int. Ed. , vol.40 , pp. 1162
  • 13
    • 0000263344 scopus 로고    scopus 로고
    • For selected references on multilayers prepared from metal complexes, see: a) M. Maskus, H. D. Abruña, Langmuir 1996, 12, 4455; b) D. A. Offord, S. B. Sachs, M. S. Ennis, T. A. Eberspacher, J. H. Griffin, C. E. D. Chidsey, J. P. Collman, J. Am. Chem. Soc. 1998, 120, 4478; c) S. Bharathi, M. Nogami, S. Ikeda, Langmuir 2001, 17, 7468; d) C. Lin, C. R. Kagan, J. Am. Chem. Soc. 2003, 125, 336.
    • (1996) Langmuir , vol.12 , pp. 4455
    • Maskus, M.1    Abruña, H.D.2
  • 14
    • 0032513716 scopus 로고    scopus 로고
    • For selected references on multilayers prepared from metal complexes, see: a) M. Maskus, H. D. Abruña, Langmuir 1996, 12, 4455; b) D. A. Offord, S. B. Sachs, M. S. Ennis, T. A. Eberspacher, J. H. Griffin, C. E. D. Chidsey, J. P. Collman, J. Am. Chem. Soc. 1998, 120, 4478; c) S. Bharathi, M. Nogami, S. Ikeda, Langmuir 2001, 17, 7468; d) C. Lin, C. R. Kagan, J. Am. Chem. Soc. 2003, 125, 336.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 4478
    • Offord, D.A.1    Sachs, S.B.2    Ennis, M.S.3    Eberspacher, T.A.4    Griffin, J.H.5    Chidsey, C.E.D.6    Collman, J.P.7
  • 15
    • 0035960801 scopus 로고    scopus 로고
    • For selected references on multilayers prepared from metal complexes, see: a) M. Maskus, H. D. Abruña, Langmuir 1996, 12, 4455; b) D. A. Offord, S. B. Sachs, M. S. Ennis, T. A. Eberspacher, J. H. Griffin, C. E. D. Chidsey, J. P. Collman, J. Am. Chem. Soc. 1998, 120, 4478; c) S. Bharathi, M. Nogami, S. Ikeda, Langmuir 2001, 17, 7468; d) C. Lin, C. R. Kagan, J. Am. Chem. Soc. 2003, 125, 336.
    • (2001) Langmuir , vol.17 , pp. 7468
    • Bharathi, S.1    Nogami, M.2    Ikeda, S.3
  • 16
    • 0037438483 scopus 로고    scopus 로고
    • For selected references on multilayers prepared from metal complexes, see: a) M. Maskus, H. D. Abruña, Langmuir 1996, 12, 4455; b) D. A. Offord, S. B. Sachs, M. S. Ennis, T. A. Eberspacher, J. H. Griffin, C. E. D. Chidsey, J. P. Collman, J. Am. Chem. Soc. 1998, 120, 4478; c) S. Bharathi, M. Nogami, S. Ikeda, Langmuir 2001, 17, 7468; d) C. Lin, C. R. Kagan, J. Am. Chem. Soc. 2003, 125, 336.
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 336
    • Lin, C.1    Kagan, C.R.2
  • 17
    • 0037860477 scopus 로고    scopus 로고
    • note
    • 2] (py=pyridine) by using bpy instead of py. Synthetic details and full characterization data are provided in Supporting Information.
  • 31
    • 0038198220 scopus 로고    scopus 로고
    • note
    • A larger amount of charge of the CO-bound cluster relative to the CO-free cluster (here the 1:1 stoichiometry is expected) arises from physical adsorption of 1, which was not removed from the surface by rinsing with water. This situation is also encountered for the following CO-terminated multilayers.
  • 32
    • 0037860479 scopus 로고    scopus 로고
    • note
    • The kinetic aspect of the CO dissociation from the multilayers will be detailed in our future publication.
  • 33
    • 0037522881 scopus 로고    scopus 로고
    • note
    • -1. All these infrared spectroscopic features are similar to the triruthenium derivatives as well as their monolayers prepared on Au. Upon electrolysis, the intensity of the v(CO) band decreases significantly.
  • 34
    • 0037522870 scopus 로고    scopus 로고
    • note
    • s(COO)].
  • 35
    • 0037860480 scopus 로고    scopus 로고
    • note
    • The relative intensity ratio of the two peaks is examined rather than their absolute intensity, because desorption of Au from the Au substrate surface was apparent during the immersion process for deposition, which directly affects the intensity of the infrared band.
  • 36
    • 0038536883 scopus 로고    scopus 로고
    • note
    • 1/2 by 0.05 V.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.