Study of the lithiated phenylacetonitrile monoanions and dianions formed according to the lithiated base used (LHMDS, LDA, or n-BuLi). 1. Evidence of heterodimer ("Quadac") or dianion formation by vibrational spectroscopy

Journal of Organic Chemistry

Volumn 68, Issue 10, 2003, Pages 3902-3911

  Corset, Jacques ^a   Castellà Ventura, Martine ^a   Froment, Françoise ^a   Strzalko, Tekla ^b   Wartski, Lya ^b  

^a UMR 8233 CNRS Université Pierre et Marie Curie   (France)

^b CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; DECOMPOSITION; DIMERS; ENTROPY; MOLECULAR VIBRATIONS; MONOMERS; SPECTROSCOPIC ANALYSIS; TOLUENE;

HETERODIMERS;

ACETONITRILE;

BENZYL CYANIDE DERIVATIVE; HEXANE; TOLUENE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); ENTROPY; EQUILIBRIUM CONSTANT; LITHIATION; MASS SPECTROMETRY; MOLECULAR STABILITY; REACTION ANALYSIS; STRUCTURE ANALYSIS; VIBRATIONAL SPECTROSCOPY;

EID: 0038627515     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo020492t     Document Type: Article

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