Raman spectroscopy as a probe of low-temperature ionic speciation in nitric and sulfuric acid stratospheric mimic systems

Journal of Physical Chemistry A

Volumn 107, Issue 22, 2003, Pages 4436-4444

  Minogue, Nicholas ^a   Riordan, Eoin ^a   Sodeau, John R ^a  

^a UNIVERSITY COLLEGE CORK   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

MIMIC SYSTEMS;

FREEZING; IONS; LOW TEMPERATURE EFFECTS; PROTONS; RAMAN SPECTROSCOPY;

NITRIC ACID;

EID: 0038511081     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp021746h     Document Type: Article

References (45)

1. Finlayson-Pitts, B. J.; Pius, J, N., Jr. Chemistry of the Upper and Lower Atmosphere; Academic Press: New York, 2000.
2. 2O solutions at stratospheric temperatures: Nucleation statistics and experiments. J. Phys. Chem. A 1997, 101, 1117-1133.
3. Peter, T. Microphysics and heterogeneous chemistry of polar stratospheric clouds. Annu, Rev. Phys. Chem. 1997, 48, 785-822.
4. Reichardt, J.; Tsias, A.; Behrendt, A. Optical properties of PSC Ia - Enhanced at UV - visible wavelengths: Model and observations. Geophys. Res. Lett. 2000, 27, 201-204.
5. 2O, Including Solubilities of HBr, From <200 to 328 K. J. Phys. Chem. 1995, 99, 11557-11574.
6. Carslaw, K. S.; Peter, T.; Clegg, S. L. Modeling the composition of liquid stratospheric aerosols. Rev. Geophys. 1997, 35, 125-154.
7. 2O particles upon cooling: Implications for polar stratospheric clouds. Science 1996, 272, 1638-1641.
8. Koop, T.; Carslaw, K. S.; Peter, T. Thermodynamic stability and phase transitions of PSC particles. Geophys. Res. Lett. 1997, 24, 2199-2202.
9. European Union Press Release. "Severe stratospheric ozone depletion in the Arctic" European Commission, 2000. http://www.nilu.no/projects/ theseo2000/press-rel-000405.htm.
10. Kirk-Davidoff, D. B.; Hintsa, E. J.; Anderson, J. O.; Keith, D. W. The effect of climate change on ozone depletion through changes in stratospheric water vapour. Nature 1999, 402, 399-401.
11. 2O films - formation, water-uptake, and solid-liquid phase changes. J. Geophys. Res.-Atmos. 1993, 95, 20473-20481.
12. Anthony, S. E.; Tisdale, R. T.; Disselkamp, R. S.; Tolbert, M. A.; Wilson, J. C. FT-IR studies of low-temperature sulfuric acid aerosols. Geophys. Res. Lett. 1995, 22, 1105-1108.
13. 2O Solutions at Stratospheric Temperatures: Nucleation Statistics and Experiments. J. Phys. Chem. A 1997, 101, 1117-1133.
14. 2O system - Implications for polar stratospheric clouds. Science 1993, 261, 1418-1423.
15. 2O mixtures at stratospheric temperatures. Abstr. Pap. Am. Chem. Soc. 1990, 200, 29.
16. Fox, L. E.; Worsnop, D. R.; Zahniser, M. S.; Wofsy, S. C. Metastable phases in polar stratospheric aerosols. Science 1995, 267, 351-355.
17. 2O solutions at stratospheric temperatures. Geophys. Res. Lett. 2000, 27, 193-196.
18. Schreiner, J.; Voigt, G.; Kohlmann, A.; Arnold, F.; Mauersberger, K.; Larsen, N. Chemical analysis of polar stratospheric cloud particles. Science 1999, 283, 968-970.
19. Horn, A. B.; Sully, K. J. ATR-IR spectroscopic studies of the formation of sulfuric acid and sulfuric acid monohydrate films. Phys. Chem. Chem. Phys. 1999, 1, 3801-3806.
20. Koch, T. G.; Holmes, N. S.; Roddis, T. B.; Sodeau, J. R. Low-temperature reflection/absorption IR study of thin films of nitric acid hydrates and ammonium nitrate adsorbed on gold foil. J. Chem. Soc., Faraday Trans. 1996, 92, 4787-4792.
21. Iraci, L. T.; Middlebrook, A. M.; Wilson, M. A.; Tolbert, M. A. Growth of nitric acid hydrates on thin sulfuric acid films. Geophys. Res. Lett. 1994, 21, 867-870.
22. K. L.; Sully, J. K.; Horn, A. B. Infrared spectroscopic studies of the low-temperature interconversion of sulfuric acid hydrates. Submitted to Phys, Chem. Chem. Phys.
23. 2O/HCl solutions at 200 K. J. Atmos. Chem. 1999, 32, 315-325.
24. Tolbert, M. A.; Rossi, M. J.; Golden, D. M. Heterogeneous interactions of chlorine nitrate, hydrogen chloride, and nitric acid with sulfuric acid surfaces at stratospheric temperatures. Geophys. Res. Lett. 1988, 15, 847-850.
25. 2O solutions. Faraday Discuss. 1995, 269-278.
26. 5 by sulfuric acid solutions. J. Geophys. Res. - Atmos. 1997, 102, 3583-3601.
27. 2O mixtures. J. Phys. Chem. A 1998,702, 4794-4807.
28. Zhang, R. Y.; Leu, M. T.; Molina, M. J. Formation of polar stratospheric clouds on preactivated background aerosols. Geophys. Res. Lett. 1996, 25, 1669-1672.
29. 4 at low temperature. J. Chem. Eng. Data 1996, 41, 765-778.
30. Librovich, N. B.; Rassadin, B. V.; Medvetskaya, I. M.; Andreeva, L. R.; Vinnik, M. I. Raman spectra of nitric acid in aqueous sulfuric acid solutions. Bull. Acad. Sci. USSR Div. Chem. Sci. 1984, 33, 401-1405.
31. Edwards, H. G. M.; Turner. J. M. C.; Fawcett, V. Raman spectroscopic study of nitronium ion formation in mixtures of nitric acid, sulfuric acid and water. J. Chem. Sec., Faraday Trans. 1995, 91, 1439-1443.
32. Edwards, H. G. M.; Fawcett, V. Quantitative raman spectroscopic studies of nitronium ion concentrations in mixtures of sulfuric and nitric acids. J. Mol. Struct. 1994, 326, 131-143.
33. Ocean Optics Ltd. Manufacturer's Websile, 2000, www.OceanOptics.com.
34. Visonex Ltd. Manufacturer's Website, 2000, www.visionex.com.
35. Ratcliffe, C. I.; Irish, D. E. Vibrational spectral studies of solutions at elevated temperatures and pressures 0.7. Raman spectra and dissociation of nitric acid. Can. J. Chem - Rev. Can. Chim. 1985, 63, 3521-3525.
36. Young, T. F.; Maranville, L. F.; Smith, H. M. In The Structure of Electrolyte Solutions', Hamer, W. J., Ed.; Wiley and Sons: New York, 1959; Chapter 4.
37. 2- equilibrium. J. Phys. Chem. 1986, 90, 334-341.
38. 3 system. Bull. Chem. Soc. Jpn. 1982, 55, 1645-1646.
39. Fletcher, N. H. The chemical physics of ice; Cambridge University Press: Cambridge, U.K., 1970.
40. Tomikawa, K.; Kanno, H. Raman study of sulfuric acid at low temperatures. J. Phys. Chem. A 1998, 702, 6082-6088.
41. Kanno, H. Complete ionization of concentrated sulfuric acid at low temperatures. Chem. Phys. Lett. 1990, 170, 382-384.
42. +. Personal communication.
43. 2O solutions. J. Phys. Chem. A 1999, 103, 2673-2679.
44. 2. J. Phys. Chem. 1991, 95, 6182-6186.
45. 3 mole fractions <0.5. J. Geophys. Res. 2000, 105, 9283-9290.