Metal-bis[poly(pyrazolyl)borate] complexes. Electrochemical, magnetic, and spectroscopic properties and coupled electron-transfer and spin-exchange reactions

Inorganic Chemistry

Volumn 42, Issue 11, 2003, Pages 3616-3622

  De Alwis, D Chanaka L ^a   Schultz, Franklin A ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BORIC ACID; LIGAND; METAL;

ARTICLE; COMPLEX FORMATION; CYCLIC POTENTIOMETRY; ELECTROCHEMISTRY; ELECTRON; ELECTRON TRANSPORT; INFRARED SPECTROSCOPY; MAGNETISM; OXIDATION REDUCTION POTENTIAL; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 0038016951     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034077a     Document Type: Article

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63. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
64. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
65. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
66. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
67. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
68. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
69. 3+/2+ electron self-exchange rates are topics that have been discussed for many years. For a selection of experimental and theoretical treatments of the problem see: (a) Buhks, E.; Dixon, M.; Jortner, J.; Navon, G. Inorg. Chem. 1979, 18, 2014. (b) Endicott, J. F.; Brubaker, G. R.; Ramasami, T.; Kumar, K.; Dwarakanath, K.; Cassel, J.; Johnson, D. Inorg. Chem. 1983, 22, 3754. (c) Hammershøi, A.; Geselowitz, D.; Taube, H. Inorg. Chem. 1984, 32, 979. (d) Larsson, S.; Ståhl, K.; Zerner, M. C. Inorg. Chem. 1986, 25, 3033. (e) Newton, M. D. J. Phys. Chem. 1991, 95, 30. (f) Shalders, R. D.; Swaddle, T. W. Inorg. Chem. 1995, 34, 4815. (g) Bernhardt, P. V.; Jones, L. A.; Sharpe, P. C. Inorg. Chem. 1997, 36, 2420. (h) Endres, R. G.; LaBute, M. X.; Cox, D. L. Los Alamos National Laboratory, Preprint Archive, Physics 2002, 1-10. arXiv:physics/ 0212010. http://xxx.lan1.gov/pdf/physics/0212010.
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