Electrochemical influence of tridentate polypyrazolylborate ligands: Syntheses and electrochemistry of bis(η3-polypyrazolylborato)ruthenium(II) complexes

Chemistry Letters

Volumn , Issue 2, 2001, Pages 96-97

  Onishi, Masayoshi ^a   Kumagae, Siho ^a   Asai, Keiko ^a   Kawano, Hiroyuki ^a   Shigemitsu, Yasuhiro ^b  

^a NAGASAKI UNIVERSITY   (Japan)

^b INDUSTRIAL TECHNOLOGY CENTER OF NAGASAKI   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035639507     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.96     Document Type: Article

References (23)

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16. 4, respectively.
17. 2]; 1, -77 mV; 2, -202 mV; 3, 247 mV; 4, -248 mV; 5, -350 mV; 6, -135 mV; 7, 87 mV; 8, -156 mV; 9, -212 mV.
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21. 8 and was not responsible to the different electrochemical properties of their ruthenium(II) complexes.
22. 3Ru moieties. Electron-withdrawing character of pyrazolyl groups is clearly exemplified by the well-known acidic property of their 1-N protons in pyrazoles.
23. 4. The authors expect that the EHMO calculations and molecular orbital analyses will give useful clues to the π-bonding effects on the electrochemical properties of the ruthenium complexes.