Synthesis of reactive poly(vinyl oxazolones) via nitroxide-mediated "living" free radical polymerization

Macromolecules

Volumn 36, Issue 12, 2003, Pages 4302-4308

  Tully, David C ^a   Roberts, Michael J ^a   Geierstanger, Bernhard H ^a   Grubbs, Robert B ^b  

^a GENOMICS INSTITUTE OF THE NOVARTIS RESEARCH FOUNDATION   (United States)

^b Dartmouth College   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; BLOCK COPOLYMERS; COPOLYMERIZATION; FREE RADICAL POLYMERIZATION; HOMOPOLYMERIZATION; INITIATORS (CHEMICAL); LIVING POLYMERIZATION; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; MONOMERS; STYRENE; SYNTHESIS (CHEMICAL);

NITROXIDE; NUCLEOPHILES; POLYDISPERSITY; POLYVINYL OXAZOLONES; VINYLDIMETHYLOXAZOLONE;

VINYL RESINS;

EID: 0037898899     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma025817m     Document Type: Article

References (24)

1. Heilmann, S. M.; Rasmussen, J. K.; Krepski, L. R. J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 3655-3677 and references therein.
2. Taylor, L. D.; Chiklis, C. K.; Platt, T. E. Polym. Lett. 1971, 9, 187-190.
3. Taylor, L. D.; Kolensinski, H. S.; Mehta, A. C.; Locatell, L.; Larson, P. S. Makromol. Chem. Rapid Commun. 1982, 3, 779-782.
4. Coleman, P. L.; Walker, M. M.; Milbrath, D. S.; Stauffer, D. M.; Rasmussen, J. K.; Krepski, L. R.; Heilmann, S. M. J. Chromatogr. 1990, 512, 345-363.
5. Drtina, G. J.; Heilmann, S. M.; Moren, D. M.; Rasmussen, J. K.; Krepski, L. R.; Smith, H. K., II; Pranis, R. A.; Turek, T. C. Macromolecules 1996, 29, 4486-4489.
6. Peterson, D. S.; Rohr, T.; Svec, F.; Fréchet, J. M. J. Anal. Chem. 2002, 74, 4081-4088.
7. Xie, S.; Svec, F.; Fréchet, J. M. J. Biotechnol. Bioeng. 1999, 62, 29-35.
8. Tripp, J. A.; Stein, J. A.; Svec, F.; Fréchet, J. M. J. Org. Lett. 2000, 2, 195-198
9. Tripp, J. A.; Svec, F.; Fréchet, J. M. J. J. Comb. Chem. 2001, 3, 216-223.
10. Iwakura, Y.; Toda, F.; Torii, Y. J. Polym. Sci., Part A-1 1966, 4, 2649-2657.
11. Iwakura, Y.; Toda, F.; Torii, Y.; Sekii, R. J. Polym. Sci., Part A-1 1968, 4, 2681-2686.
12. Muthiah, J.; Mathias, L. J. J. Polym. Sci., Part A: Polym. Chem. 1991, 29, 29-37.
13. Fazio, R. C.; Grasshoff, J. M.; Taylor, L. D. J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 329-331.
14. Rasmussen, J. K.; Heilmann, S. M.; Krepski, L. R. In Encyclopedia of Polymer Science and Engineering, 2nd ed.; Wiley: New York, 1988; Chapter 11, pp 558-571 and references therein.
15. Matyjaszewski, K.; Xia, J. Chem. Rev. 2001, 101, 2921-2990 and references therein.
16. Coessens, V.; Pintauer, T.; Matyjaszewski, K. Prog. Polym. Sci. 2001, 26, 337-377 and references therein.
17. Hawker, C. J.; Bosman, A. W.; Harth, E. Chem. Rev. 2001, 101, 3661-3688 and references therein.
18. Benoit, D.; Chaplinski, V.; Braslau, R.; Hawker, C. J. J. Am. Chem. Soc. 1999, 121, 3904-3920.
19. Benoit, D.; Harth, E.; Fox, P.; Waymouth, R. M.; Hawker, C. J. Macromolecules 2000, 33, 363-370.
20. Grimaldi, S.; Finet, J. P.; Le Moigne, F.; Zeghdaoui, A.; Tordo, P.; Benoit, D.; Fontanille, M.; Gnanou, Y. Macromolecules 2000, 33, 1141-1147.
21. Benoit, D.; Grimaldi, S.; Robin, S.; Finet, J. P.; Tordo, P.; Gnanou, Y. J. Am. Chem. Soc. 2000, 122, 5929-5939.
22. Robin, S.; Guerret, O.; Courturier, J. L.; Pirri, R.; Gnanou, Y. Macromolecules 2002 35, 3844-3848.
23. Malmström E.; Miller R. D.; Hawker, C. J. Tetrahedron 1997, 53, 15225-15236.
24. 1H NMR by comparing resonance of methyl groups in polymer (1.36 ppm, broad singlet) with that of the monomer (1.46 ppm, singlet).