Nanoscale palladium cluster immobilized on a TiO2 surface as an efficient catalyst for liquid-phase wacker oxidation of higher terminal olefins

Chemistry Letters

Volumn 32, Issue 2, 2003, Pages 180-181

  Choi, Kwang Min ^a   Mizugaki, Tomoo ^a   Ebitani, Kohki ^a   Kaneda, Kiyotomi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; COPPER CHLORIDE; OXYGEN; PALLADIUM; TITANIUM DIOXIDE;

ARTICLE; ATMOSPHERE; CATALYST; IMMOBILIZATION; LIQUID; NANOPARTICLE; OXIDATION;

EID: 0037883463     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.180     Document Type: Article

References (19)

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2. An excellent review of the Wacker oxidation: J. Tsuji, Synthesis, 1984, 369; J. Tsuji, "Palladium Reagents and Catalysts Innovations in Organic Synthesis," John Wiley & Sons, New York (1998).
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14. 2 reference samples.
15. 2O (0.5 mL), and 1-decene (0.14 g, 1 mmol) was added. Then, the reaction mixture was vigorously stirred at 80°C for 2 h. The catalyst was separated by filtration, and GC analysis of the filtrate showed 88% yield of 2-decanone.
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