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33645910979
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12 Isomerized alkenes were detected by GLC analyses.
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12 Isomerized alkenes were detected by GLC analyses.
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25
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33645906684
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13 Similar results were observed in the aerobic oxidation of alcohols when the reaction was carried out at a temperature close to the boiling point of the solvent; ref. 10b.
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13 Similar results were observed in the aerobic oxidation of alcohols when the reaction was carried out at a temperature close to the boiling point of the solvent; ref. 10b.
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26
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33645902287
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note
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1H NMR of the crude reaction mixture did not show any signals due to the aldehyde proton in low field, suggesting that the oxidation of the hydroxy group in 1d may be slower than that of a terminal alkene.
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27
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33645946178
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2 catalytic system yielded undec-10-en-l-al in 91% yield after 17 h; unpublished results.
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2 catalytic system yielded undec-10-en-l-al in 91% yield after 17 h; unpublished results.
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28
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33645929523
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2), but overoxidation proceeded to give acefophenone as a major product. In our present system, the formation of acetophenone was not observed.
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2), but overoxidation proceeded to give acefophenone as a major product. In our present system, the formation of acetophenone was not observed.
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31
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33947482604
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