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Volumn , Issue 12, 2000, Pages 1915-1918

Palladium(II)-catalyzed oxidation of terminal alkenes to methyl ketones using molecular oxygen

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; KETONES; OXIDATION; OXYGEN; PALLADIUM COMPOUNDS; REDUCTION;

EID: 0034697701     PISSN: 14704358     EISSN: None     Source Type: Journal    
DOI: 10.1039/b001854f     Document Type: Article
Times cited : (108)

References (31)
  • 23
    • 0002993450 scopus 로고
    • For cobalt(II)-complex catalyzed aerobic oxidation of alkenes using an alcohol as reductant, see: T. Mukaiyama and T. Yamada, Bull. Chem. Soc. Jpn., 1995, 68, 17.
    • (1995) Bull. Chem. Soc. Jpn. , vol.68 , pp. 17
    • Mukaiyama, T.1    Yamada, T.2
  • 24
    • 33645910979 scopus 로고    scopus 로고
    • 12 Isomerized alkenes were detected by GLC analyses.
    • 12 Isomerized alkenes were detected by GLC analyses.
  • 25
    • 33645906684 scopus 로고    scopus 로고
    • 13 Similar results were observed in the aerobic oxidation of alcohols when the reaction was carried out at a temperature close to the boiling point of the solvent; ref. 10b.
    • 13 Similar results were observed in the aerobic oxidation of alcohols when the reaction was carried out at a temperature close to the boiling point of the solvent; ref. 10b.
  • 26
    • 33645902287 scopus 로고    scopus 로고
    • note
    • 1H NMR of the crude reaction mixture did not show any signals due to the aldehyde proton in low field, suggesting that the oxidation of the hydroxy group in 1d may be slower than that of a terminal alkene.
  • 27
    • 33645946178 scopus 로고    scopus 로고
    • 2 catalytic system yielded undec-10-en-l-al in 91% yield after 17 h; unpublished results.
    • 2 catalytic system yielded undec-10-en-l-al in 91% yield after 17 h; unpublished results.
  • 28
    • 33645929523 scopus 로고    scopus 로고
    • 2), but overoxidation proceeded to give acefophenone as a major product. In our present system, the formation of acetophenone was not observed.
    • 2), but overoxidation proceeded to give acefophenone as a major product. In our present system, the formation of acetophenone was not observed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.