Proton-induced change of the coordination mode of a boron group: Boryl complexes [Mn(CO)4(PR3)(BH2·PMe3) and cationic borane σ complexes [Mn(CO)4(PR3)(η1-BH3 ·PMe3)]

Angewandte Chemie - International Edition

Volumn 42, Issue 15, 2003, Pages 1727-1730

  Yasue, Takahiro ^a   Kawano, Yasuro ^a   Shimoi, Mamoru ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Boranes; Boron; Coordination modes; Manganese; Protonation

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; COORDINATION REACTIONS; DECOMPOSITION; POSITIVE IONS;

PROTONATION;

BORON COMPOUNDS;

BORANE DERIVATIVE; BORON DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; GEOMETRY; ION PAIR CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE; PHOTOLYSIS; POLARIZATION; PROTON TRANSPORT; SOLID STATE;

EID: 0037879292     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200219992     Document Type: Article

References (28)

1. R. H. Crabtree, Acc. Chem. Res. 1990, 23, 95.
2. R. H. Morris, P. G. Jessop, Coord. Chem. Rev. 1992, 121, 155.
3. D. M. Heinkey, W. J. Oldham, Jr., Chem. Rev. 1993, 93, 913.
4. R. H. Crabtree, Angew. Chem. 1993, 105, 823; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
5. R. H. Crabtree, Angew. Chem. 1993, 105, 823; Angew. Chem. Int. Ed. Engl. 1993, 32, 789.
6. G. J. Kubas, Metal Dihydrogen and σ-Bond Complexes, Kluwer Academic/Plenum Publishers, New York, 2001.
7. 3]: F. R. Lemke, J. Am. Chem. Soc. 1994, 116, 11183; S. T. N. Freeman, F. R. Lemke, L. Brammer, Organometallics 2002, 21, 2030;
8. 3]: F. R. Lemke, J. Am. Chem. Soc. 1994, 116, 11183; S. T. N. Freeman, F. R. Lemke, L. Brammer, Organometallics 2002, 21, 2030;
9. 3]: E. Scharrer, S. Chang, M. Brookhart, Organometallics 1995, 14, 5686.
10. Y. Kawano, T. Yasue, M. Shimoi, J. Am. Chem. Soc. 1999, 121, 11744.
11. T. Yasue, Y. Kawano, M. Shimoi, Chem. Lett. 2000, 58.
12. M. Shimoi, S. Nagai, M. Ichikawa, Y. Kawano, K. Katoh, M. Uruichi, H. Ogino, J. Am. Chem. Soc. 1999, 121, 11704.
13. T. Kakizawa, Y. Kawano, M. Shimoi, Organometallics 2001, 20, 3211.
14. o), 296 parameters, GoF = 1.110. The boron-attached hydrogen atoms were found by the difference Fourier syntheses and their positions were refined. CCDC-190001 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ ccdc.cam.ac.uk).
15. K. M. Waltz, H. He, C. N. Muhoro, J. F. Hartwig, J. Am. Chem. Soc. 1995, 117, 11357.
16. M. Brookhart, B. Grant, A. F. Vople, Jr., Organometallics 1992, 11, 3920.
17. R. Macías, N. P. Rath, L. Barton, Angew. Chem. 1999, 111, 203; Angew. Chem. Int. Ed. 1999, 38, 162.
18. R. Macías, N. P. Rath, L. Barton, Angew. Chem. 1999, 111, 203; Angew. Chem. Int. Ed. 1999, 38, 162.
19. M. Ingleson, N. J. Patmore, G. D. Ruggiero, C. G. Frost, M. F. Mahon, M. C. Willis, A. S. Weller, Organometallics 2001, 20, 4434.
20. [17]
21. Gaussian98 (Revision A.11), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J., B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian, Inc., Pittsburgh, PA, 2001.
22. + (L = neutral Lewis base) have been reported: P. Kölle, H. Nöth, Chem. Rev. 1985, 85, 399.
23. a) J. Huhmann-Vincent, B. L. Scott, G. J. Kubas, Inorg. Chim. Acta 1999, 294, 240;
24. b) J. Huhmann-Vincent, B. L. Scott, G. J. Kubas, J. Am. Chem. Soc. 1998, 120, 6808;
25. c) X. Fang, J. Huhmann-Vincent, B. L. Scott, G. J. Kubas, J. Organomet. Chem. 2000, 609, 95;
26. d) J. Huhmann-Vincent, B. L. Scott, G. J. Kubas, Inorg. Chem. 1999, 38, 115
27. e) X. Fang, B. L. Scott, K. D. John, G. J. Kubas, Organometallics 2000, 19, 4141.
28. E. D. Glendening, A. E. Reed, J. E. Carpenter, F. Weinhold, NBO version 3.1.